We present results from a coordinated IR-to-X-ray spectral campaign of the QSO IRAS 13349+2438. Optical spectra reveal extreme Eigenvector-1 characteristics, but the H-beta line width argues against a NLS1 classification; we refine z=0.10853 based on
[O III]. We estimate a BH mass=10^9 Msun using 2 independent methods (H-beta line width & SED fits). Blue-shifted absorption (-950km/s & -75km/s) is seen for the 1st time in STIS UV spectra from Ly-alpha, NV, & CIV. The higher velocity UV lines are coincident with the lower-ionisation (xi~1.6) X-ray warm absorber lines. A dusty multiple ionization absorber blueshifted by 700-900km/s is required to fit the X-ray data. Theoretical models comparing different ionising SEDs reveal that a UV-inclusive (i.e., the accretion disc) ionising continuum strongly impacts conclusions for the thermodynamic stability of the warm absorber. Specific to IRAS13349, an Xray-UV ionising SED favors a continuous distribution of ionisation states in a smooth flow (this paper), versus discrete clouds in pressure equilibrium (work by others where UV is omitted). Direct dust detections are seen in both the IR: PAH emission at (7.7 & 11.3)micron which may also be blended with forsterite, and (10 & 18)micron silicate emission, and X-rays: iron dust with a dust-to-gas ratio > 90%. We develop a geometrical model whereby the QSO nuclear region is viewed through the upper atmosphere of an obscuring torus. This sight line is obscured by dust that blocks a direct view of the UV/optical emission region but is largely transparent in X-rays since the gas is ionised. In our model, 20% of the intrinsic UV/optical continuum is scattered into our sight line by the far wall of an obscuring torus. An additional 2.4% of the direct light, which likely dominates the UV emission, is Thomson-scattered into our line-of-sight by another off-plane component of highly ionized gas.
We present a new technique for determining the *quantity and composition* of dust in astrophysical environments using <6keV X-rays. We argue that high resolution X-ray spectra as enabled by the Chandra and XMM-Newton gratings should be considered a p
owerful and viable new resource for delving into a relatively unexplored regime for directly determining dust properties: composition, quantity, and distribution. We present initial cross-section measurements of astrophysically likely iron-based dust candidates taken at the Lawrence Berkeley National Laboratory Advanced Light Source synchrotron beamline, as an illustrative tool for the formulation of our methodology. Focused at the 700eV Fe LIII and LII photoelectric edges, we discuss a technique for modeling dust properties in the soft X-rays using L-edge data, to complement K-edge X-ray absorption fine structure analysis techniques discussed in Lee & Ravel 2005. This is intended to be *a techniques paper* of interest and usefulness to both condensed matter experimentalists and astrophysicists. For the experimentalists, we offer a new prescription for normalizing relatively low S/N L-edge cross section measurements. For astrophysics interests, we discuss the use of X-ray absorption spectra for determining dust composition in cold and ionized astrophysical environments, and a new method for determining *species-specific gas-to-dust ratios*. Possible astrophysical applications of interest, are offered. Prospects for improving on this work with future X-ray missions with higher throughput and spectral resolution are presented in the context of spectral resolution goals for gratings and calorimeters, for proposed and planned missions such as Astro-H and the International X-ray Observatory.
The abundances of gas and dust (solids and complex molecules) in the interstellar medium (ISM) as well as their composition and structures impact practically all of astrophysics. Fundamental processes from star formation to stellar winds to galaxy fo
rmation all scale with the number of metals. However, significant uncertainties remain in both absolute and relative abundances, as well as how these vary with environment, e.g., stellar photospheres versus the interstellar medium (ISM). While UV, optical, IR, and radio studies have considerably advanced our understanding of ISM gas and dust, they cannot provide uniform results over the entire range of column densities needed. In contrast, X-rays will penetrate gas and dust in the cold (3K) to hot (100,000,000K) Universe over a wide range of column densities (log NH=20-24 cm^-2), imprinting spectral signatures that reflect the individual atoms which make up the gas, molecule or solid. *X-rays therefore are a powerful and viable resource for delving into a relatively unexplored regime for determining gas abundances and dust properties such as composition, charge state, structure, and quantity via absorption studies, and distribution via scattering halos.*
