Diffraction phenomena usually can be formulated in terms of a potential that induces the redistribution of a waves momentum. Using an atomic Bose-Einstein condensate coupled to the orbitals of a state-selective optical lattice, we investigate a hithe
rto unexplored nonadiabatic regime of diffraction in which no diffracting potential can be defined, and in which the adiabatic dressed states are strongly mixed. We show how, in the adiabatic limit, the observed coupling between internal and external dynamics gives way to standard Kapitza-Dirac diffraction of atomic matter waves. We demonstrate the utility of our scheme for atom interferometry and discuss prospects for studies of dissipative superfluid phenomena.
