The chemical evolution in high-mass star-forming regions is still poorly constrained. Studying the evolution of deuterated molecules allows to differentiate between subsequent stages of high-mass star formation regions due to the strong temperature d
ependence of deuterium isotopic fractionation. We observed a sample of 59 sources including 19 infrared dark clouds, 20 high-mass protostellar objects, 11 hot molecular cores and 9 ultra-compact HII regions in the (3-2) transitions of the four deuterated molecules, DCN, DNC, DCO+ and N2D+ as well as their non-deuterated counterpart. The overall detection fraction of DCN, DNC and DCO+ is high and exceeds 50% for most of the stages. N2D+ was only detected in a few infrared dark clouds and high-mass protostellar objects. It can be related to problems in the bandpass at the frequency of the transition and to low abundances in the more evolved, warmer stages. We find median D/H ratios of ~0.02 for DCN, ~0.005 for DNC, ~0.0025 for DCO+ and ~0.02 for N2D+. While the D/H ratios of DNC, DCO+ and N2D+ decrease with time, DCN/HCN peaks at the hot molecular core stage. We only found weak correlations of the D/H ratios for N2D+ with the luminosity of the central source and the FWHM of the line, and no correlation with the H2 column density. In combination with a previously observed set of 14 other molecules (Paper I) we fitted the calculated column densities with an elaborate 1D physico-chemical model with time-dependent D-chemistry including ortho- and para-H2 states. Good overall fits to the observed data have been obtained the model. It is one of the first times that observations and modeling have been combined to derive chemically based best-fit models for the evolution of high-mass star formation including deuteration.
Context: How do molecular clouds form out of the atomic phase? And what are the relative fractions of carbon in the ionized, atomic and molecular phase? These are questions at the heart of cloud and star formation. Methods: Using multiple observatori
es from Herschel and SOFIA to APEX and the IRAM 30m telescope, we mapped the ionized, atomic and molecular carbon ([CII]@1900GHz, [CI]@492GHz and C18O(2-1)@220GHz) at high spatial resolution (12-25) in four young massive infrared dark clouds (IRDCs). Results: The three carbon phases were successfully mapped in all four regions, only in one source the [CII] line remained a non-detection. Both the molecular and atomic phases trace the dense structures well, with [CI] also tracing material at lower column densities. [CII] exhibits diverse morphologies in our sample, from compact to diffuse structures probing the cloud environment. In at least two out of the four regions, we find kinematic signatures strongly indicating that the dense gas filaments have formed out of a dynamically active and turbulent atomic/molecular cloud, potentially from converging gas flows. The atomic-to-molecular carbon gas mass ratios are low between 7% and 12% with the lowest values found toward the most quiescent region. In the three regions where [CII] is detected, its mass is always higher by a factor of a few than that of the atomic carbon. The ionized carbon emission depends as well on the radiation field, however, we also find strong [CII] emission in a region without significant external sources, indicating that other processes, e.g., energetic gas flows can contribute to the [CII] excitation as well.
Aims: We study the fragmentation and dynamical properties of a massive starless gas clump at the onset of high-mass star formation. Methods: Based on Herschel continuum data we identify a massive gas clump that remains far-infrared dark up to 100mum
wavelengths. The fragmentation and dynamical properties are investigated by means of Plateau de Bure Interferometer and Nobeyama 45m single-dish spectral line and continuum observations. Results: The massive gas reservoir fragments at spatial scales of ~18000AU in four cores. Comparing the spatial extent of this high-mass region with intermediate- to low-mass starless cores from the literature, we find that linear sizes do not vary significantly over the whole mass regime. However, the high-mass regions squeeze much more gas into these similar volumes and hence have orders of magnitude larger densities. The fragmentation properties of the presented low-to high-mass regions are consistent with gravitational instable Jeans fragmentation. Furthermore, we find multiple velocity components associated with the resolved cores. Recent radiative transfer hydrodynamic simulations of the dynamic collapse of massive gas clumps also result in multiple velocity components along the line of sight because of the clumpy structure of the regions. This result is supported by a ratio between viral and total gas mass for the whole region <1. Conclusions: This apparently still starless high-mass gas clump exhibits clear signatures of early fragmentation and dynamic collapse prior to the formation of an embedded heating source. A comparison with regions of lower mass reveals that the linear size of star-forming regions does not necessarily have to vary much for different masses, however, the mass reservoirs and gas densities are orders of magnitude enhanced for high-mass regions compared to their lower-mass siblings.
While most sources above 10^5Lsun have already formed an Ultracompact HII region (UCHII), this is not necessarily the case for sources of lower luminosity. Characterizing sources in the transition phase, i.e., very luminous objects without any detect
able free-free emission, is important for a general understanding of massive star formation. Therefore, we observed the luminous High-Mass Protostellar Object IRAS23151+5912 with the Submillimeter Array at 875mum in the submm continuum and spectral line emission at sub-arcsecond resolution. The 875mum submm continuum emission has been resolved into at least two condensations. The previously believed driving source of one of the outflows, the infrared source IRS1, is ~0.9 offset from the main submm peak. Over the entire 4GHz bandwidth we detect an intermediate dense spectral line forest with 27 lines from 8 different species, isotopologues or vibrationally-torsionally excited states. Temperature estimates based on the CH3OH line series result in values of T(Peak1)~150+-50K and T(Peak2)~80~30K for the two submm peak positions, respectively. The SiO(8-7) red- and blue-shifted line maps indicate the presence of two molecular outflows. In contrast, the vibrationally-torsionally excited CH3OH line exhibits a velocity gradient approximately perpendicular to one of the outflows. With a size of approximately 5000AU and no Keplerian rotation signature, this structure does not resemble a genuine accretion disk but rather a larger-scale rotating toroid that may harbor a more common accretion disk at its so far unresolved center.
