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The LUMINEU program aims at performing a pilot experiment on neutrinoless double beta decay of 100Mo using radiopure ZnMoO4 crystals operated as scintillating bolometers. Growth of high quality radiopure crystals is a complex task, since there are no commercially available molybdenum compounds with the required levels of purity and radioactive contamination. This paper discusses approaches to purify molybdenum and synthesize compound for high quality radiopure ZnMoO4 crystal growth. A combination of a double sublimation (with addition of zinc molybdate) with subsequent recrystallization in aqueous solutions (using zinc molybdate as a collector) was used. Zinc molybdate crystals up to 1.5 kg were grown by the low-thermal-gradient Czochralski technique, their optical, luminescent, diamagnetic, thermal and bolometric properties were tested.
The Workshop on results of the Project Kosmomikrofizyka-2 (Astroparticle Physics) of the National Academy of Sciences (NAS) of Ukraine Astrophysical and cosmological problems of invisible mass and dark energy in the Universe was held on November 21-2 2, 2012 in the Institute for Nuclear Research, Kyiv, Ukraine (http://lpd.kinr.kiev.ua/kmf12). This Project was carried out during three years (2010-2012) by scientists from various universities and institutes of the National Academy of Sciences of Ukraine; it was a logical continuation of the previous scientific program of the NAS of Ukraine Researches of structure and composition of the Universe, hidden mass and dark energy (Kosmomikrofizyka) in 2007-2009. These programs were devoted to theoretical and experimental investigations in astronomy, astrophysics, cosmology, physics of atomic nuclei and particle physics, which are related with the problems of dark matter and dark energy in the Universe.
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