ترغب بنشر مسار تعليمي؟ اضغط هنا

Recent theoretical advances predict the existence, deep into the glass phase, of a novel phase transition, the so-called Gardner transition. This transition is associated with the emergence of a complex free energy landscape composed of many marginal ly stable sub-basins within a glass metabasin. In this study, we explore several methods to detect numerically the Gardner transition in a simple structural glass former, the infinite-range Mari-Kurchan model. The transition point is robustly located from three independent approaches: (i) the divergence of the characteristic relaxation time, (ii) the divergence of the caging susceptibility, and (iii) the abnormal tail in the probability distribution function of cage order parameters. We show that the numerical results are fully consistent with the theoretical expectation. The methods we propose may also be generalized to more realistic numerical models as well as to experimental systems.
As a guideline for experimental tests of the ideal glass transition (Random Pinning Glass Transition, RPGT) that shall be induced in a system by randomly pinning particles, we performed first-principle computations within the Hypernetted chain approx imation and numerical simulations of a Hard Sphere model of glass-former. We obtain confirmation of the expected enhancement of glassy behaviour under the procedure of random pinning, which consists in freezing a fraction $c$ of randomly chosen particles in the positions they have in an equilibrium configuration. We present the analytical phase diagram as a function of $c$ and of the packing fraction $phi$, showing a line of RPGT ending in a critical point. We also obtain first microscopic results on cooperative length-scales characterizing medium-range amorphous order in Hard Spere glasses and indirect quantitative information on a key thermodynamic quantity defined in proximity of ideal glass transitions, the amorphous surface tension. Finally, we present numerical results of pair correlation functions able to differentiate the liquid and the glass phases, as predicted by the analytic computations.
109 - G. Parisi , B. Seoane 2013
We show in numerical simulations that a system of two coupled replicas of a binary mixture of hard spheres undergoes a phase transition in equilibrium at a density slightly smaller than the glass transition density for an unreplicated system. This re sult is in agreement with the theories that predict that such a transition is a precursor of the standard ideal glass transition. The critical properties are compatible with those of an Ising system. The relations of this approach to the conventional approach based on configurational entropy are briefly discussed.
mircosoft-partner

هل ترغب بارسال اشعارات عن اخر التحديثات في شمرا-اكاديميا