The Chamaeleon clouds are excellent targets for low-mass star formation studies. Cha I and II are actively forming stars while Cha III shows no sign of ongoing star formation. We aim to determine the driving factors that have led to the very differen
t levels of star formation activity in Cha I and III and examine the dynamical state and possible evolution of the starless cores within them. Observations were performed in various molecular transitions with APEX and Mopra. Five cores are gravitationally bound in Cha I and one in Cha III. The infall signature is seen toward 8-17 cores in Cha I and 2-5 cores in Cha III, which leads to a range of 13-28% of the cores in Cha I and 10-25% of the cores in Cha III that are contracting and may become prestellar. Future dynamical interactions between the cores will not be dynamically significant in either Cha I or III, but the subregion Cha I North may experience collisions between cores within ~0.7 Myr. Turbulence dissipation in the cores of both clouds is seen in the high-density tracers N2H+ 1-0 and HC3N 10-9. Evidence of depletion in the Cha I core interiors is seen in the abundance distributions of C17O, C18O, and C34S. Both contraction and static chemical models indicate that the HC3N to N2H+ abundance ratio is a good evolutionary indicator in the prestellar phase for both gravitationally bound and unbound cores. In the framework of these models, we find that the cores in Cha III and the southern part of Cha I are in a similar evolutionary stage and are less chemically evolved than the central region of Cha I. The measured HC3N/N2H+ abundance ratio and the evidence for contraction motions seen towards the Cha III starless cores suggest that Cha III is younger than Cha I Centre and that some of its cores may form stars in the future. The cores in Cha I South may on the other hand be transient structures. (abridged)
The largest non-cyclic molecules detected in the interstellar medium (ISM) are organic with a straight-chain carbon backbone. We report an interstellar detection of a branched alkyl molecule, iso-propyl cyanide (i-C3H7CN), with an abundance 0.4 times
that of its straight-chain structural isomer. This detection suggests that branched carbon-chain molecules may be generally abundant in the ISM. Our astrochemical model indicates that both isomers are produced within or upon dust grain ice mantles through the addition of molecular radicals, albeit via differing reaction pathways. The production of iso-propyl cyanide appears to require the addition of a functional group to a non-terminal carbon in the chain. Its detection therefore bodes well for the presence in the ISM of amino acids, for which such side-chain structure is a key characteristic.
In recent years, organic molecules of increasing complexity have been found toward the prolific Galactic center source Sagittarius B2. We wish to explore the degree of complexity that the interstellar chemistry can reach in star-forming regions. We c
arried out a complete line survey of the hot cores Sgr B2(N) and (M) with the IRAM 30 m telescope in the 3 mm range. We analyzed this spectral survey in the LTE approximation. We modeled the emission of all known molecules simultaneously, which allows us to search for less abundant, more complex molecules. We compared the derived column densities with the predictions of a coupled gas-phase and grain-surface chemical code. We report the first detection in space of ethyl formate (C2H5OCHO) and n-propyl cyanide (C3H7CN) toward Sgr B2(N). The abundances of ethyl formate and n-propyl cyanide relative to H2 are estimated to be 3.6e-9 and 1.0e-9, respectively. Our chemical modeling suggests that the sequential, piecewise construction of ethyl and n-propyl cyanide from their constituent functional groups on the grain surfaces is their most likely formation route. Ethyl formate is primarily formed on the grains by adding CH3 to functional-group radicals derived from methyl formate, although ethanol may also be a precursor. The detection in Sgr B2(N) of the next stage of complexity in two classes of complex molecule, esters and alkyl cyanides, suggests that greater complexity in other classes of molecule may be present in the interstellar medium. {Abridged}
