We derive an equality for non-equilibrium statistical mechanics in finite-dimensional quantum systems. The equality concerns the worst-case work output of a time-dependent Hamiltonian protocol in the presence of a Markovian heat bath. It has has the
form worst-case work = penalty - optimum. The equality holds for all rates of changing the Hamiltonian and can be used to derive the optimum by setting the penalty to 0. The optimum term contains the max entropy of the initial state, rather than the von Neumann entropy, thus recovering recent results from single-shot statistical mechanics. Energy coherences can arise during the protocol but are assumed not to be present initially. We apply the equality to an electron box.
In quantum theory, particles in three spatial dimensions come in two different types: bosons or fermions, which exhibit sharply contrasting behaviours due to their different exchange statistics. Could more general forms of probabilistic theories admi
t more exotic types of particles? Here, we propose a thought experiment to identify more exotic particles in general post-quantum theories. We consider how in quantum theory the phase introduced by swapping indistinguishable particles can be measured. We generalise this to post-quantum scenarios whilst imposing indistinguishability and locality principles. We show that our ability to witness exotic particle exchange statistics depends on which symmetries are admitted within a theory. These exotic particles can manifest unusual behaviour, such as non-abelianicity even in topologically simple three-dimensional space.
