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45 - E.M. Foard , A.J. Wagner 2009
Enslaved phase-separation fronts that move with a speed just smaller than that of a free front will leave in their wake a morphology of alternating domains that are roughly aligned with the front. However, these alternating domains will typically not be in phase initially. Instead there are defects. Here we present novel phase-separation morphologies that are formed in such systems where the defects are reminiscent of spiral dislocations in crystal growth.
83 - A.J. Wagner , C.M. Pooley 2007
Simulations of liquid-gas systems with extended interfaces are observed to fail to give accurate results for two reasons: the interface can get ``stuck on the lattice or a density overshoot develops around the interface. In the first case the bulk de nsities can take a range of values, dependent on the initial conditions. In the second case inaccurate bulk densities are found. In this communication we derive the minimum interface width required for the accurate simulation of liquid gas systems with a diffuse interface. We demonstrate this criterion for lattice Boltzmann simulations of a van der Waals gas. When combining this criterion with predictions for the bulk stability we can predict the parameter range that leads to stable and accurate simulation results. This allows us to identify parameter ranges leading to high density ratios of over 1000. This is despite the fact that lattice Boltzmann simulations of liquid-gas systems were believed to be restricted to modest density ratios of less than 20.
121 - Qun Li , A.J. Wagner 2007
We present a lattice Boltzmann algorithm based on an underlying free energy that allows the simulation of the dynamics of a multicomponent system with an arbitrary number of components. The thermodynamic properties, such as the chemical potential of each component and the pressure of the overall system, are incorporated in the model. We derived a symmetrical convection diffusion equation for each component as well as the Navier Stokes equation and continuity equation for the overall system. The algorithm was verified through simulations of binary and ternary systems. The equilibrium concentrations of components of binary and ternary systems simulated with our algorithm agree well with theoretical expectations.
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