We report 250 GHz (1.2 mm) observations of a sample of 20 QSOs at redshifts 5.8<z<6.5 from the the Canada-France High-z Quasar Survey (CFHQS), using the Max-Planck Millimeter Bolometer (MAMBO) array at the IRAM 30-metre telescope. A rms sensitivity <
~ 0.6 mJy was achieved for 65% of the sample, and <~ 1.0 mJy for 90%. Only one QSO, CFHQS J142952+544717, was robustly detected with S_250GHz = 3.46 +/-0.52 mJy. This indicates that one of the most powerful known starbursts at z~6 is associated with this radio loud QSO. On average, the other CFHQS QSOs, which have a mean optical magnitude fainter than previously studied SDSS samples of z~6 QSOs, have a mean 1.2 mm flux density <S_250GHz> = 0.41 +/-0.14 mJy; such a 2.9-sigma average detection is hardly meaningful. It would correspond to <L_FIR> ~ 0.94+/-0.32 10^12 Lo, and an average star formation rate of a few 100s Mo/yr, depending on the IMF and a possible AGN contribution to <L_FIR>. This is consistent with previous findings of Wang et al. (2011) on the far-infrared emission of z~6 QSOs and extends them toward optically fainter sources.
Using IRAM PdBI we report the detection of H2O in six new lensed ultra-luminous starburst galaxies at high redshift, discovered in the Herschel H-ATLAS survey. The sources are detected either in the 2_{02}-1_{11} or 2_{11}-2_{02} H_2O emission lines
with integrated line fluxes ranging from 1.8 to 14 Jy.km/s. The corresponding apparent luminosities are mu x L_H2O ~ 3-12 x 10^8 Lo, where mu is the lensing magnification factor (3 < mu < 12). These results confirm that H2O lines are among the strongest molecular lines in such galaxies, with intensities almost comparable to those of the high-J CO lines, and same profiles and line widths (200-900 km/s) as the latter. With the current sensitivity of PdBI, H2O can therefore easily be detected in high-z lensed galaxies (with F(500um) > 100 mJy) discovered in the Herschel surveys. Correcting the luminosities for lensing amplification, L_H2O is found to have a strong dependence on the IR luminosity, varying as ~L_IR^{1.2}. This relation which needs to be confirmed with better statistics, may indicate a role of radiative (IR) excitation of the H2O lines, and implies that high-z galaxies with L_IR >~ 10^13 Lo tend to be very strong emitters in H2O, that have no equivalent in the local universe.
The Herschel survey, H-ATLAS, with its large areal coverage, has recently discovered a number of bright, strongly lensed high-z submillimeter galaxies. The strong magnification makes it possible to study molecular species other than CO, which are oth
erwise difficult to observe in high-z galaxies. Among the lensed galaxies already identified by H-ATLAS, the source J090302.9-014127B (SDP.17b) at z = 2.305 is remarkable due to its excitation conditions and a tentative detection of the H2O 202-111 emission line (Lupu et al. 2010). We report observations of this line in SDP.17b using the IRAM interferometer equipped with its new 277- 371GHz receivers. The H2O line is detected at a redshift of z = 2.3049+/-0.0006, with a flux of 7.8+/-0.5 Jy km s-1 and a FWHM of 250+/-60 km s-1. The new flux is 2.4 times weaker than the previous tentative detection, although both remain marginally consistent within 1.6-sigma. The intrinsic line luminosity and ratio of H2O(202-111)/CO8-7 seem comparable with those of the nearby starburst/enshrouded-AGN Mrk 231, suggesting that SDP.17b could also host a luminous AGN. The detection of a strong H2O 202-111 line in SDP.17b implies an efficient excitation mechanism of the water levels that must occur in very dense and warm interstellar gas.
The main achievements, current developments and prospects of molecular studies in external galaxies are reviewed. They are put in the context of the results of several decades of studies of molecules in local interstellar medium, their chemistry and
their importance for star formation. CO observations have revealed the gross structure of molecular gas in galaxies. Together with other molecules, they are among the best tracers of star formation at galactic scales. Our knowledge about molecular abundances in various local galactic environments is progressing. They trace physical conditions and metallicity, and they are closely related to dust processes and large aromatic molecules. Major recent developments include mega-masers, and molecules in Active Galactic Nuclei; millimetre emission of molecules at very high redshift; and infrared H2 emission as tracer of warm molecular gas, shocks and photodissociation regions. The advent of sensitive giant interferometers from the centimetre to sub-millimetre range, especially ALMA in the near future in the mm/submm range, will open a new area for molecular studies in galaxies and their use to trace star formation at all distances.
