The kinetics of the transformation from the hexagonal packed cylinder (HEX) phase to the face-centered-cubic (FCC) phase was simulated using Brownian Dynamics for an ABA triblock copolymer in a selective solvent for the A block. The kinetics was obta
ined by instantaneously changing either the temperature of the system or the well-depth of the Lennard-Jones potential. Detailed analysis showed that the transformation occurred via a rippling mechanism. The simulation results indicated that the order-order transformation (OOT) was a nucleation and growth process when the temperature of the system instantly jumped from 0.8 to 0.5. The time evolution of the structure factor obtained by Fourier Transformation showed that the peak intensities of the HEX and FCC phases could be fit well by an Avrami equation.
Time-resolved small angle x-ray scattering (SAXS) was used to examine the kinetics of the transition from HEX cylinders to BCC spheres at various temperatures in poly(styrene-b- ethylene-co-butylene-b-styrene) (SEBS) in mineral oil, a selective solve
nt for the middle EB block. Temperature-ramp SAXS and rheology measurements show the HEX to BCC order-order transition (OOT) at ~127 oC and order-disorder transition (ODT) at ~180 oC. We also observed the metastability limit of HEX in BCC with a spinodal temperature, Ts ~ 150 oC. The OOT exhibits 3 stages and occurs via a nucleation and growth mechanism when the final temperature Tf < Ts. Spinodal decomposition in a continuous ordering system was seen when Ts< Tf < TODT. We observed that HEX cylinders transform to disordered spheres via a transient BCC state. We develop a geometrical model of coupled anisotropic fluctuations and calculate the scattering which shows very good agreement with the SAXS data. The splitting of the primary peak into two peaks when the cylinder spacing and modulation wavelength are incommensurate predicted by the model is confirmed by analysis of the SAXS data.
We examined the kinetics of the transformation from the lamellar (LAM) to the hexagonally packed cylinder (HEX) phase for the triblock copolymer, polystyrene-b-poly (ethylene-co-butylene)-b-polystyrene (SEBS) in dibutyl phthalate (DBP), a selective s
olvent for polystyrene (PS), using time-resolved small angle x-ray scattering (SAXS). We observe the HEX phase with the EB block in the cores at a lower temperature than the LAM phase due to the solvent selectivity of DBP for the PS block. Analysis of the SAXS data for a deep temperature quench well below the LAM-HEX transition shows that the transformation occurs in a one-step process. We calculate the scattering using a geometric model of rippled layers with adjacent layers totally out of phase during the transformation. The agreement of the calculations with the data further supports the continuous transformation mechanism from the LAM to HEX for a deep quench. In contrast, for a shallow quench close to the OOT we find agreement with a two-step nucleation and growth mechanism.
