C$_{60}$ in Photodissociation Regions

Recent studies have confirmed the presence of buckminsterfullerene (C$_{60}$) in different interstellar and circumstellar environments. However, several aspects regarding C$_{60}$ in space are not well understood yet, such as the formation and excitation processes, and the connection between C$_{60}$ and other carbonaceous compounds in the interstellar medium, in particular polycyclic aromatic hydrocarbons (PAHs). In this paper we study several photodissociation regions (PDRs) where C$_{60}$ and PAHs are detected and the local physical conditions are reasonably well constrained, to provide observational insights into these questions. C$_{60}$ is found to emit in PDRs where the dust is cool ($T_d = 20-40$ K) and even in PDRs with cool stars. These results exclude the possibility for C$_{60}$ to be locked in grains at thermal equilibrium in these environments. We observe that PAH and C$_{60}$ emission are spatially uncorrelated and that C$_{60}$ is present in PDRs where the physical conditions (in terms of radiation field and hydrogen density) allow for full dehydrogenation of PAHs, with the exception of Ced 201. We also find trends indicative of an increase in C$_{60}$ abundance within individual PDRs, but these trends are not universal. These results support models where the dehydrogenation of carbonaceous species is the first step towards C$_{60}$ formation. However, this is not the only parameter involved and C$_{60}$ formation is likely affected by shocks and PDR age.

PDR Model Mapping of Obscured H2 Emission and the Line-of-Sight Structure of M17-SW

We observed H2 line emission with Spitzer-IRS toward M17-SW and modeled the data with our PDR code. Derived gas density values of up to few times 10^7 cm^-3 indicate that H2 emission originates in high-density clumps. We discover that the PDR code can be utilized to map the amount of intervening extinction obscuring the H2 emission layers, and thus we obtain the radial profile of A_V relative to the central ionizing cluster NGC 6618. The extinction has a positive radial gradient, varying between 15--47 mag over the projected distance of 0.9--2.5 pc from the primary ionizer, CEN 1. These high extinction values are in good agreement with previous studies of A_V toward stellar targets in M17-SW. The ratio of data to PDR model values is used to infer the global line-of-sight structure of the PDR surface, which is revealed to resemble a concave surface relative to NGC 6618. Such a configuration confirms that this PDR can be described as a bowl-shaped boundary of the central H II region in M17. The derived structure and physical conditions are important for interpreting the fine-structure and rotational line emission from the PDR.