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169 - X. Luo , Y. S. Oh , A. Sirenko 2012
We discovered that perovskite (Ba,La)SnO3 can have excellent carrier mobility even though its band gap is large. The Hall mobility of Ba0.98La0.02SnO3 crystals with the n-type carrier concentration of sim 8-10times10 19 cm-3 is found to be sim 103 cm 2 V-1s-1 at room temperature, and the precise measurement of the band gap Delta of a BaSnO3 crystal shows Delta=4.05 eV, which is significantly larger than those of other transparent conductive oxides. The high mobility with a wide band gap indicates that (Ba,La)SnO3 is a promising candidate for transparent conductor applications and also epitaxial all-perovskite multilayer devices.
The study of abrupt increases in magnetization with magnetic field known as metamagnetic transitions has opened a rich vein of new physics in itinerant electron systems, including the discovery of quantum critical end points with a marked propensity to develop new kinds of order. However, the electric analogue of the metamagnetic critical end point, a metaelectric critical end point has not yet been realized. Multiferroic materials wherein magnetism and ferroelectricity are cross-coupled are ideal candidates for the exploration of this novel possibility using magnetic-field (emph{H}) as a tuning parameter. Herein, we report the discovery of a magnetic-field-induced metaelectric transition in multiferroic BiMn$_{2}$O$_{5}$ in which the electric polarization (emph{P}) switches polarity along with a concomitant Mn spin-flop transition at a critical magnetic field emph{H}$_{rm c}$. The simultaneous metaelectric and spin-flop transitions become sharper upon cooling, but remain a continuous crossover even down to 0.5 K. Near the emph{P}=0 line realized at $mu_{0}$emph{H}$_{rm c}$$approx$18 T below 20 K, the dielectric constant ($varepsilon$) increases significantly over wide field- and temperature (emph{T})-ranges. Furthermore, a characteristic power-law behavior is found in the emph{P}(emph{H}) and $varepsilon$(emph{H}) curves at emph{T}=0.66 K. These findings indicate that a magnetic-field-induced metaelectric critical end point is realized in BiMn$_2$O$_5$ near zero temperature.
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