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Josephson junctions with topological insulator weak links can host low energy Andreev bound states giving rise to a current phase relation that deviates from sinusoidal behaviour. Of particular interest are zero energy Majorana bound states that form at a phase difference of $pi$. Here we report on interferometry studies of Josephson junctions and superconducting quantum interference devices (SQUIDs) incorporating topological insulator weak links. We find that the nodes in single junction diffraction patterns and SQUID oscillations are lifted and independent of chemical potential. At high temperatures, the SQUID oscillations revert to conventional behaviour, ruling out asymmetry. The node lifting of the SQUID oscillations is consistent with low energy Andreev bound states exhibiting a nonsinusoidal current phase relation, coexisting with states possessing a conventional sinusoidal current phase relation. However, the finite nodal currents in the single junction diffraction pattern suggest an anomalous contribution to the supercurrent possibly carried by Majorana bound states, although we also consider the possibility of inhomogeneity.
Bi2Se3 is one of a handful of known topological insulators. Here we show that copper intercalation in the van der Waals gaps between the Bi2Se3 layers, yielding an electron concentration of ~ 2 x 10^20cm-3, results in superconductivity at 3.8 K in Cu xBi2Se3 for x between 0.12 and 0.15. This demonstrates that Cooper pairing is possible in Bi2Se3 at accessible temperatures, with implications for study of the physics of topological insulators and potential devices.
Photoemission experiments have shown that Bi$_2$Se$_3$ is a topological insulator. By controlled doping, we have obtained crystals of Bi$_2$Se$_3$ with non-metallic conduction. At low temperatures, we uncover a novel type of magnetofingerprint signal which involves the spin degrees of freedom. Given the mm-sized crystals, the observed amplitude is 200-500$times$ larger than expected from universal conductance fluctuations. The results point to very long phase breaking lengths in an unusual conductance channel in these non-metallic samples. We discuss the nature of the in-gap conducting states and their relation to the topological surface states.
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