Observationally, the interstellar gas-phase abundance of deuterium (D) is considerably depleted and the missing D atoms are often postulated to have been locked up into carbonaceous solids and polycyclic aromatic hydrocarbon (PAH) molecules. An accur
ate knowledge of the fractional amount of D (relative to H) tied up in carbon dust and PAHs has important cosmological implications since D originated exclusively from the Big Bang and the present-day D abundance, after accounting for the astration it has experienced during the Galactic evolution, provides essential clues to the primordial nucleosynthesis and the cosmological parameters. To quantitatively explore the extent to which PAHs could possibly accommodate the observed D depletion, we have previously quantum-chemically computed the infrared vibrational spectra of mono-deuterated PAHs and derived the mean intrinsic band strengths of the 3.3 $mu$m C--H stretch (A$_{3.3}$) and the 4.4 $mu$m C--D stretch (A$_{4.4}$). Here we extend our previous work to multi-deuterated PAH species of different deuterations, sizes and structures. We find that both the intrinsic band strengths A$_{3.3}$ and A$_{4.4}$ and their ratios A$_{4.4}$/A$_{3.3}$ not only show little variations among PAHs of different deuterations, sizes and structures, they are also closely similar to that of mono-deuterated PAHs. Therefore, a PAH deuteration level (i.e., the fraction of peripheral atoms attached to C atoms in the form of D) of ~2.4% previously estimated from the observed 4.4 $mu$m to 3.3 $mu$m band ratio based on the A$_{4.4}$/A$_{3.3}$ ratio of mono-deuterated PAHs is robust.
We performed a Cr-K emission line survey in young supernova remnants (SNRs) with the Chandra archival data. Our sample includes W49B, Cas A, Tycho and Kepler. We confirmed the existence of the Cr line in W49B and discovered this emission line in the
other three SNRs. The line center energies, equivalent widths (EWs) and fluxes of the Cr lines are given. The Cr in Cas A is in a high ionization state while that in Tycho and Kepler is in a much lower one. We find a good positive correlation between Cr and Fe line center energies, suggesting a common origin of Cr and Fe in the nucleosynthesis, which is consistent with the theoretical predictions. We propose that the EW ratio between Cr and Fe can be used as a supplementary constraint on the progenitors properties and the explosion mechanism.
