The fundamental assumption of statistical mechanics is that the system is equally likely in any of the accessible microstates. Based on this assumption, the Boltzmann distribution is derived and the full theory of statistical thermodynamics can be bu
ilt. In this paper, we show that the Boltzmann distribution in general can not describe the steady state of open system. Based on the effective Hamiltonian approach, we calculate the specific heat, the free energy and the entropy for an open system in steady states. Examples are illustrated and discussed.
By using the effective Hamiltonian approach, we present a self-consistent framework for the analysis of geometric phases and dynamically stable decoherence-free subspaces in open systems. Comparisons to the earlier works are made. This effective Hami
ltonian approach is then extended to a non-Markovian case with the generalized Lindblad master equation. Based on this extended effective Hamiltonian approach, the non-Markovian master equation describing a dissipative two-level system is solved, an adiabatic evolution is defined and the corresponding adiabatic condition is given.
