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We present the first three-dimensional radiation-magnetohydrodynamic simulations of the photoionisation of a dense, magnetised molecular globule by an external source of ultraviolet radiation. We find that, for the case of a strong ionising field, si gnificant deviations from the non-magnetic evolution are seen when the initial magnetic field threading the globule has an associated magnetic pressure that is greater than one hundred times the gas pressure. In such a strong-field case, the photoevaporating globule will adopt a flattened or curled up shape, depending on the initial field orientation, and magnetic confinement of the ionised photoevaporation flow can lead to recombination and subsequent fragmentation during advanced stages of the globule evolution. We find suggestive evidence that such magnetic effects may be important in the formation of bright, bar-like emission features in H II regions. We include simple but realistic fits to heating and cooling rates in the neutral and molecular gas in the vicinity of a high-mass star cluster and show that the frequently used isothermal approximation can lead to an overestimate of the importance of gravitational instability in the radiatively imploded globule. For globules within 2 parsecs of a high-mass star cluster, we find that heating by stellar x rays prevents the molecular gas from cooling below 50 K.
The hydrogen ionization and dissociation front around an ultraviolet radiation source should merge when the ratio of ionizing photon flux to gas density is sufficiently low and the spectrum is sufficiently hard. This regime is particularly relevant t o the molecular knots that are commonly found in evolved planetary nebulae, such as the Helix Nebula, where traditional models of photodissociation regions have proved unable to explain the high observed luminosity in H_2 lines. In this paper we present results for the structure and steady-state dynamics of such advection-dominated merged fronts, calculated using the Cloudy plasma/molecular physics code. We find that the principal destruction processes for H_2 are photoionization by extreme ultraviolet radiation and charge exchange reactions with protons, both of which form H_2^+, which rapidly combines with free electrons to undergo dissociative recombination. Advection moves the dissociation front to lower column densities than in the static case, which vastly increases the heating in the partially molecular gas due to photoionization of He^0, H_2, and H^0. This causes a significant fraction of the incident bolometric flux to be re-radiated as thermally excited infrared H_2 lines, with the lower excitation pure rotational lines arising in 1000 K gas and higher excitation H_2 lines arising in 2000 K gas, as is required to explain the H_2 spectrum of the Helix cometary knots.
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