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$alpha$-clustering structure is a significant topic in light nuclei. A Bayesian convolutional neural network (BCNN) is applied to classify initial non-clustered and clustered configurations, namely Woods-Saxon distribution and three-$alpha$ triangula r (four-$alpha$ tetrahedral) structure for $^{12}$C ($^{16}$O), from heavy-ion collision events generated within a multi-phase transport (AMPT) model. Azimuthal angle and transverse momentum distributions of charged pions are taken as inputs to train the classifier. On multiple-event basis, the overall classification accuracy can reach $95%$ for $^{12}$C/$^{16}$O + $^{197}$Au events at $sqrt{S_{NN}} =$ 200 GeV. With proper constructions of samples, the predicted deviations on mixed samples with different proportions of both configurations could be within $5%$. In addition, setting a simple confidence threshold can further improve the predictions on the mixed dataset. Our results indicate promising and extensive possibilities of application of machine-learning-based techniques to real data and some other problems in physics of heavy-ion collisions.
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