Mid-infrared spectra of 65 T Tauri stars (TTS) taken with the Infrared Spectrograph (IRS) on board the Spitzer Space Telescope are modeled using dust at two temperatures to probe the radial variation in dust composition in the uppermost layers of pro
toplanetary disks. Most spectra indicating crystalline silicates require Mg-rich minerals and silica, but a few suggest otherwise. Spectra indicating abundant enstatite at higher temperatures also require crystalline silicates at temperatures lower than those required for spectra showing high abundance of other crystalline silicates. A few spectra show 10 micron complexes of very small equivalent width. They are fit well using abundant crystalline silicates but very few large grains, inconsistent with the expectation that low peak-to-continuum ratio of the 10 micron complex always indicates grain growth. Most spectra in our sample are fit well without using the opacities of large crystalline silicate grains. If large grains grow by agglomeration of submicron grains of all dust types, the amorphous silicate components of these aggregates must typically be more abundant than the crystalline silicate components. Crystalline silicate abundances correlate positively with other such abundances, suggesting that crystalline silicates are processed directly from amorphous silicates and that neither forsterite, enstatite, nor silica are intermediate steps when producing either of the other two. Disks with more dust settling typically have greater crystalline abundances. Large-grain abundance is somewhat correlated with greater settling of disks. The lack of strong correlation is interpreted to mean that settling of large grains is sensitive to individual disk properties. Lower-mass stars have higher abundances of large grains in their inner regions.
Mid-infrared spectra of a few T Tauri stars (TTS) taken with the Infrared Spectrograph (IRS) on board the Spitzer Space Telescope show prominent narrow emission features indicating silica (crystalline silicon dioxide). Silica is not a major constitue
nt of the interstellar medium; therefore, any silica present in the circumstellar protoplanetary disks of TTS must be largely the result of processing of primitive dust material in the disks surrouding these stars. We model the silica emission features in our spectra using the opacities of various polymorphs of silica and their amorpho
We present spectra of a sample of Herbig Ae and Be (HAeBe) stars obtained with the Infrared Spectrograph on the Spitzer Space Telescope. All but one of the Herbig stars show emission from polycyclic aromatic hydrocarbons (PAHs) and seven of the spect
ra show PAH emission, but no silicate emission at 10 microns. The central wavelengths of the 6.2, 7.7--8.2, and 11.3 micron emission features decrease with stellar temperature, indicating that the PAHs are less photo-processed in cooler radiation fields. The apparent low level of photo processing in HAeBe stars, relative to other PAH emission sources, implies that the PAHs are newly exposed to the UV-optical radiation fields from their host stars. HAeBe stars show a variety of PAH emission intensities and ionization fractions, but a narrow range of PAH spectral classifications based on positions of major PAH feature centers. This may indicate that, regardless of their locations relative to the stars, the PAH molecules are altered by the same physical processes in the proto-planetary disks of intermediate-mass stars. Analysis of the mid-IR spectral energy distributions indicates that our sample likely includes both radially flared and more flattened/settled disk systems, but we do not see the expected correlation of overall PAH emission with disk geometry. We suggest that the strength of PAH emission from HAeBe stars may depend not only on the degree of radial flaring, but also on the abundance of PAHs in illuminated regions of the disks and possibly on the vertical structure of the inner disk as well.
