The parent compounds of the recently discovered iron-arsenic (pnictide) high temperature superconductors transition into an intriguing spin density wave (SDW) phase at low temperatures. Progress in understanding this SDW state has been complicated by
a complex band structure and by the fact that the spin, electronic, and structural degrees of freedom are closely intertwined in these compounds. Scanning tunneling microscopy (STM) measurements have added to this complexity by revealing different topographies with no consensus on the surface structure. In this paper, we use a combination of high-resolution STM imaging and spectroscopy, and low energy electron diffraction (LEED) to determine the atomic and electronic structure of the parent pnictide SrFe2As2. Our data present a compelling picture of the existence of two coexisting homotopic structures on the surface. Based on this, we construct a simple model for the surface, which offers an explanation of the two classes of topographies seen by STM. STM spectroscopy shows that while the high energy density of states (DOS) profile is consistent with the Fe 3d and As 4p-electrons predicted by LDA it is in better agreement with calculations that include electron correlations beyond LDA. Importantly, we find a gap of ~15 meV in the low energy density of states on both structures which may be linked with the SDW or the observed surface reconstruction.
