The fluctuations of a Markovian jump process with one or more unidirectional transitions, where $R_{ij} >0$ but $R_{ji} =0$, are studied. We find that such systems satisfy an integral fluctuation theorem. The fluctuating quantity satisfying the theor
em is a sum of the entropy produced in the bidirectional transitions and a dynamical contribution which depends on the residence times in the states connected by the unidirectional transitions. The convergence of the integral fluctuation theorem is studied numerically, and found to show the same qualitative features as in systems exhibiting microreversibility.
Nonlinear optical signals from an assembly of N noninteracting particles consist of an incoherent and a coherent component, whose magnitudes scale sim N and sim N(N-1), respectively. A unified microscopic description of both types of signals is devel
oped using a quantum electrodynamical (QED) treatment of the optical fields. Closed nonequilibrium Greens function expressions are derived that incorporate both stimulated and spontaneous processes. General (n+1)-wave mixing experiments are discussed as an example of spontaneously generated signals. When performed on a single particle, such signals cannot be expressed in terms of the nth order polarization, as predicted by the semiclassical theory. Stimulated processes are shown to be purely incoherent in nature. Within the QED framework, heterodyne-detected wave mixing signals are simply viewed as incoherent stimulated emission, whereas homodyne signals are generated by coherent spontaneous emission.
