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We theoretically investigate the heat transfer between two metals across a vacuum gap in extreme near-field regime by quantifying the relative contribution of electrons, phonons and photons. We show that electrons play a dominant role in the heat tra nsfer between two metals at subnanometric distance subject to a temperature gradient. Moreover, we demonstrate that this effect is dramatically amplified in the presence of an applied bias voltage. These results could pave the way to novel strategies for thermal management and energy conversion in extreme near-field regime.
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