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We report measurements of resistance and ac magnetic susceptibility on FeSe single crystals under high pressure up to 27.2 kbar. The structural phase transition is quickly suppressed with pressure, and the associated anomaly is not seen above $sim$18 kbar. The superconducting transition temperature evolves nonmonotonically with pressure, showing a minimum at $sim12$ kbar. We find another anomaly at 21.2 K at 11.6 kbar. This anomaly most likely corresponds to the antiferromagnetic phase transition found in $mu$SR measurements [M. Bendele textit{et al.}, Phys. Rev. Lett. textbf{104}, 087003 (2010)]. The antiferromagnetic and superconducting transition temperatures both increase with pressure up to $sim25$ kbar and then level off. The width of the superconducting transition anomalously broadens in the pressure range where the antiferromagnetism coexists.
We have observed Shubnikov-de Haas oscillations in FeSe. The Fermi surface deviates significantly from predictions of band-structure calculations and most likely consists of one electron and one hole thin cylinder. The carrier density is in the order of 0.01 carriers/ Fe, an order-of-magnitude smaller than predicted. Effective Fermi energies as small as 3.6 meV are estimated. These findings call for elaborate theoretical investigations incorporating both electronic correlations and orbital ordering.
We report measurements of ac magnetic susceptibility $chi_{ac}$ and de Haas-van Alphen (dHvA) oscillations in KFe$_2$As$_2$ under high pressure up to 24.7 kbar. The pressure dependence of the superconducting transition temperature $T_c$ changes from negative to positive across $P_c sim 18$ kbar as previously reported. The ratio of the upper critical field to $T_c$, i.e, $B_{c2} / T_c$, is enhanced above $P_c$, and the shape of $chi_{ac}$ vs field curves qualitatively changes across $P_c$. DHvA oscillations smoothly evolve across $P_c$ and indicate no drastic change in the Fermi surface up to 24.7 kbar. Three dimensionality increases with pressure, while effective masses show decreasing trends. We suggest a crossover from a nodal to a full-gap $s$ wave as a possible explanation.
We have completely determined the Fermi surface in KFe$_2$As$_2$ via de Haas-van Alphen (dHvA) measurements. Fundamental frequencies $epsilon$, $alpha$, $zeta$, and $beta$ are observed in KFe$_2$As$_2$. The first one is attributed to a hole cylinder near the X point of the Brillouin zone, while the others to hole cylinders at the $Gamma$ point. We also observe magnetic breakdown frequencies between $alpha$ and $zeta$ and suggest a plausible explanation for them. The experimental frequencies show deviations from frequencies predicted by band structure calculations. Large effective masses up to 19 $m_e$ for $B parallel c$ have been found, $m_e$ being the free electron mass. The carrier number and Sommerfeld coefficient of the specific heat are estimated to be 1.01 -- 1.03 holes per formula unit and 82 -- 94 mJmol$^{-1}$K$^{-2}$, respectively, which are consistent with the chemical stoichiometry and a direct measure of 93 mJmol$^{-1}$K$^{-2}$ [H. Fukazawa textit{et al}., J. Phys. Soc. Jpn. textbf{80SA}, SA118 (2011)]. The Sommerfeld coefficient is about 9 times enhanced over a band value, suggesting the importance of low-energy spin and/or orbital fluctuations, and places KFe$_2$As$_2$ among strongly correlated metals. We have also performed dHvA measurements on Ba$_{0.07}$K$_{0.93}$Fe$_2$As$_2$ and have observed the $alpha$ and $beta$ frequencies.
We have observed hysteresis in superconducting resistive transition curves of Ba$_{0.07}$K$_{0.93}$Fe$_2$As$_2$ ($T_csim$8 K) below about 1 K for in-plane fields. The hysteresis is not observed as the field is tilted away from the $ab$ plane by 20$^{ circ}$ or more. The temperature and angle dependences of the upper critical field indicate a strong paramagnetic effect for in-plane fields. We suggest that the hysteresis can be attributed to a first-order superconducting transition due to the paramagnetic effect. Magnetic torque data are also shown.
We have determined the Fermi surface in KOs$_2$O$_6$ ($T_c$ = 9.6 K and $B_{c2} sim$ 32 T) via de Haas-van Alphen (dHvA) oscillation measurements and a band structure calculation. We find effective masses up to 26(1) $m_e$ ($m_e$ is the free electron mass), which are unusually heavy for compounds where the mass enhancement is mostly due to electron-phonon interactions. Orbit-resolved mass enhancement parameters $lambda_{dHvA}$ are large but fairly homogeneous, concentrated in the range 5 -- 8. We discuss origins of the large homogeneous mass enhancement in terms of rattling motion of the K ions.
Cyclotron resonance (CR) measurements for the Fe-based superconductor KFe$_2$As$_2$ are performed. One signal for CR is observed, and is attributed to the two-dimensional $alpha$ Fermi surface at the $Gamma$ point. We found a large discrepancy in the effective masses of CR [(3.4$pm$0.05)$m_e$ ($m_e$ is the free electron mass)] and de-Haas van Alphen (dHvA) results, a direct evidence of mass enhancement due to electronic correlation. A comparison of the CR and dHvA results shows that both intra- and interband electronic correlations contribute to the mass enhancement in KFe$_2$As$_2$.
We show that the Fermi surface (FS) in the antiferromagnetic phase of BaFe$_2$As$_2$ is composed of one hole and two electron pockets, all of which are three dimensional and closed, in sharp contrast to the FS observed by angle-resolved photoemission spectroscopy. Considerations on the carrier compensation and Sommerfeld coefficient rule out existence of unobserved FS pockets of significant sizes. A standard band structure calculation reasonably accounts for the observed FS, despite the overestimated ordered moment. The mass enhancement, the ratio of the effective mass to the band mass, is 2--3.
We report resistivity $rho$ and Hall effect measurements on EuFe$_2$As$_2$ at ambient pressure and 28 kbar and magnetization measurements at ambient pressure. We analyze the temperature and magnetic-field dependence of $rho$ and the Hall effect using a molecular-field theory for magnetoresistance and an empirical formula for the anomalous Hall effect and find that electron scattering due to the Eu$^{2+}$ local moments plays only a minor role in determining electronic transport properties of EuFe$_2$As$_2$.
In a recent Letter [J. K. Dong et al., Phys. Rev. Lett. 104, 087005 (2010)], Dong textit{et al}. have observed a $T^{1.5}$ dependence of resistivity $rho$ in KFe$_2$As$_2$ at the upper critical field $B_{c2}$ = 5 T parallel to the c axis and have sug gested the existence of a field-induced quantum critical point (QCP) at $B_{c2}$. In this comment, we argue that observation of a $T^{1.5}$ dependence of $rho$ in a sample showing broad resistive transitions does not constitute evidence for a QCP and that recent dHvA results do not support the proposed QCP.
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