Density-enhanced gas and dust shells in a new chemical model for IRC+10216

A new chemical model is presented for the carbon-rich circumstellar envelope of the AGB star IRC+10216. The model includes shells of matter with densities that are enhanced relative to the surrounding circumstellar medium. The chemical model uses an updated reaction network including reactions from the RATE06 database and a more detailed anion chemistry. In particular, new mechanisms are considered for the formation of CN-, C3N- and C2H-, and for the reactions of hydrocarbon anions with atomic nitrogen and with the most abundant cations in the circumstellar envelope. New reactions involving H- are included which result in the production of significant amounts of C2H- and CN- in the inner envelope. The calculated radial molecular abundance profiles for the hydrocarbons C2H, C4H and C6H and the cyanopolyynes HC3N and HC5N show narrow peaks which are in better agreement with observations than previous models. Thus, the narrow rings observed in molecular microwave emission surrounding IRC+10216 are interpreted as arising in regions of the envelope where the gas and dust densities are greater than the surrounding circumstellar medium. Our models show that CN- and C2H- may be detectable in IRC+10216 despite the very low theorised radiative electron attachment rates of their parent neutral species. We also show that magnesium isocyanide (MgNC) can be formed in the outer envelope through radiative association involving Mg+ and the cyanopolyyne species.

Cyanopolyynes and sulphur bearing species in hot cores: Chemical and line excitation models

We present results from a time dependent gas phase chemical model of a hot core based on the physical conditions of G305.2+0.2. While the cyanopolyyne HC_3N has been observed in hot cores, the longer chained species, HC_5N, HC_7N, and HC_9N have not been considered typical hot core species. We present results which show that these species can be formed under hot core conditions. We discuss the important chemical reactions in this process and, in particular, show that their abundances are linked to the parent species acetylene which is evaporated from icy grain mantles. The cyanopolyynes show promise as `chemical clocks which may aid future observations in determining the age of hot core sources. The abundance of the larger cyanopolyynes increase and decrease over relatively short time scales, ~10^2.5 years. We also discuss several sulphur bearing species. We present results from a non-LTE statistical equilibrium excitation model as a series of density, temperature and column density dependent contour plots which show both the line intensities and several line ratios. These aid in the interpretation of spectral line data, even when there is limited line information available.