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We report measurements of Little-Parks oscillation on the hierarchical honeycomb-superconducting network for investigating possible effects of hierarchical structure in terms of spatial symmetry, parity and duality. We observed an asymmetric Little-P arks oscillation about $Phi/Phi_0 = 1/2$, although spatial symmetry was kept in the network. In comparison with a regular honeycomb network, the asymmetric oscillation is attributed to hierarchy which induces mixture of commensurate and incommensurate regions. The asymmetric oscillation is found to indicate breaking of the duality of vortex configuration.
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