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We present the results of an experimental and theoretical study of the electronically excited $tripletex$ state of $^{87}$Rb$_2$ molecules. The vibrational energies are measured for deeply bound states from the bottom up to $v=15$ using laser spectro scopy of ultracold Rb$_2$ Feshbach molecules. The spectrum of each vibrational state is dominated by a 47,GHz splitting into a $cog$ and $clg$ component caused mainly by a strong second order spin-orbit interaction. Our spectroscopy fully resolves the rotational, hyperfine, and Zeeman structure of the spectrum. We are able to describe to first order this structure using a simplified effective Hamiltonian.
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