We investigate the electronic reconstruction across the tetragonal-orthorhombic structural transition in FeSe by employing polarization-dependent angle-resolved photoemission spectroscopy (ARPES) on detwinned single crystals. Across the structural tr
ansition, the electronic structures around the G and M points are modified from four-fold to two-fold symmetry due to the lifting of degeneracy in dxz/dyz orbitals. The dxz band shifts upward at the G point while it moves downward at the M point, suggesting that the electronic structure of orthorhombic FeSe is characterized by a momentum-dependent sign-changing orbital polarization. The elongated directions of the elliptical Fermi surfaces (FSs) at the G and M points are rotated by 90 degrees with respect to each other, which may be related to the absence of the antiferromagnetic order in FeSe.
We study superconducting FeSe (Tc = 9 K) exhibiting the tetragonal-orthorhombic structural transition (Ts = 90 K) without any antiferromagnetic ordering, by utilizing angle-resolved photoemission spectroscopy. In the detwinned orthorhombic state, the
energy position of the dyz orbital band at the Brillouin zone corner is 50 meV higher than that of dxz, indicating the orbital order similar to NaFeAs and BaFe2As2 families. Evidence of orbital order also appears in the hole bands at the Brillouin zone center. Precisely measured temperature dependence using strain-free samples shows that the onset of the orbital ordering (To) occurs very close to Ts, thus suggesting that the electronic nematicity above Ts is considerably weaker in FeSe compared to BaFe2As2 family.
The nature of the pseudogap in high transition temperature (high-Tc) superconducting cuprates has been a major issue in condensed matter physics. It is still unclear whether the high-Tc superconductivity can be universally associated with the pseudog
ap formation. Here we provide direct evidence of the existence of the pseudogap phase via angle-resolved photoemission spectroscopy in another family of high-Tc superconductor, iron-pnictides. Our results reveal a composition dependent pseudogap formation in the multi-band electronic structure of BaFe2(As1-xPx)2. The pseudogap develops well above the magnetostructural transition for low x, persists above the nonmagnetic superconducting dome for optimal x and is destroyed for x ~ 0.6, thus showing a notable similarity with cuprates. In addition, the pseudogap formation is accompanied by inequivalent energy shifts in xz/yz orbitals of iron atoms, indicative of a peculiar iron orbital ordering which breaks the four-fold rotational symmetry.
