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Here we study the structure of a highly ionizing shock wave in a gas of high atmospheric pressure. We take into account the gas ionization when the gas temperature reaches few orders of an ionization potential. It is shown that after gasdynamic tempe rature-raising shock and formation of a highly-ionized nonisothermal plasma $T_e>>T_i$ only the solitary ion-sound wave (soliton) can propagate in this plasma. In such a wave the charge separation occurs: electrons and ions form the double electric layer with the electric field. The shock wave form, its amplitude and front width are obtained.
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