We present the refinement of the crystal structure of charge-ordered LuFe2O4, based on single-crystal x-ray diffraction data. The arrangement of the different Fe-valence states, determined with bond-valence-sum analysis, corresponds to a stacking of
charged Fe bilayers, in contrast to the polar bilayers previously suggested. This arrangement is supported by an analysis of x-ray magnetic circular dichroism spectra, which also evidences a strong charge-spin coupling. The non-polar bilayers are inconsistent with charge order based ferroelectricity.
The influence of fast neutrons on the occupancy and the single tube resolution of ATLAS muon drift detectors was investigated by exposing a chamber built out of 3 layers of 3 short standard drift tubes to neutron flux-densities of up to 16 kHz/cm2 at
a neutron energy of E=11 MeV. Pulse shape capable NE213 scintillaton detectors and a calibrated BF3 neutron detector provided monitoring of the neutron flux-density and energy. The sensitivity of the drift chamber to the neutrons was measured to be 4*10-4 by comparing data sets with and without neutron background. For the investigation of tracks of cosmic muons two silicon-strip detectors above and underneath the chamber allow to compare measured drift-radii with reference tracks. Alternatively, the single tube resolution was determined using the triple-sum method. The comparison between data with and without neutron irradiation shows only a marginal effect on the resolution and little influence on the muon track reconstruction.
The majority of nuclei available for study in solid state Nuclear Magnetic Resonance have half-integer spin $I > 1/2 $, with corresponding electric quadrupole moment. As such, they may couple with a surrounding electric field gradient. This effect in
troduces anisotropic line broadening to spectra, arising from distinct chemical species within polycrystalline solids. In Multiple Quantum Magic Angle Spinning (MQMAS) experiments, a second frequency dimension is created, devoid of quadrupolar anisotropy. As a result, the center of gravity of peaks in the high resolution dimension is a function of isotropic second order quadrupole and chemical shift alone. However, for complex materials, these parameters take on a stochastic nature due in turn to structural and chemical disorder. Lineshapes may still overlap in the isotropic dimension, complicating the task of assignment and interpretation. A distributed computational approach is presented here which permits simulation of the two-dimensional MQMAS spectrum, generated by random variates from model distributions of isotropic chemical and quadrupole shifts. Owing to the non-convex nature of the residual sum of squares (RSS) function between experimental and simulated spectra, simulated annealing is used to optimize the simulation parameters. In this manner, local chemical environments for disordered materials may be characterized, and via a re-sampling approach, error estimates for parameters produced.
An experiment is performed where a single rubidium atom trapped within a high-finesse optical cavity emits two independently triggered entangled photons. The entanglement is mediated by the atom and is characterized both by a Bell inequality violatio
n of S=2.5, as well as full quantum-state tomography, resulting in a fidelity exceeding F=90%. The combination of cavity-QED and trapped atom techniques makes our protocol inherently deterministic - an essential step for the generation of scalable entanglement between the nodes of a distributed quantum network.
