Quantum memories are a crucial technology for enabling large-scale quantum networks through synchronisation of probabilistic operations. Such networks impose strict requirements on quantum memory, such as storage time, retrieval efficiency, bandwidth
, and scalability. On- and off-resonant ladder protocols on warm atomic vapour platforms are promising candidates, combining efficient high-bandwidth operation with low-noise on-demand retrieval. However, their storage time is severely limited by motion-induced dephasing caused by the broad velocity distribution of atoms comprising the vapour. In this paper, we demonstrate velocity selective optical pumping to overcome this decoherence mechanism. This will increase the achievable memory storage time of vapour memories. This technique can also be used for preparing arbitrarily shaped absorption profiles, for instance, preparing an atomic frequency comb absorption feature.
We demonstrate coherent storage and retrieval of pulsed light using the atomic frequency comb quantum memory protocol in a room temperature alkali vapour. We utilise velocity-selective optical pumping to prepare multiple velocity classes in the $F=4$
hyperfine ground state of caesium. The frequency spacing of the classes is chosen to coincide with the $F=4 - F=5$ hyperfine splitting of the $6^2$P$_{3/2}$ excited state resulting in a broadband periodic absorbing structure consisting of two usually Doppler-broadened optical transitions. Weak coherent states of duration $2,mathrm{ns}$ are mapped into this atomic frequency comb with pre-programmed recall times of $8,mathrm{ns}$ and $12,mathrm{ns}$, with multi-temporal mode storage and recall demonstrated. Utilising two transitions in the comb leads to an additional interference effect upon rephasing that enhances the recall efficiency.
