An Interferometric Spectral-Line and Imaging Survey of VY Canis Majoris in the 345 GHz Band

A spectral line survey of the oxygen-rich red supergiant VY Canis Majoris was made between 279 and 355 GHz with the Submillimeter Array. Two hundred twenty three spectral features from 19 molecules (not counting isotopic species of some of them) were observed, including the rotational spectra of TiO, TiO2, and AlCl for the first time in this source. The parameters and an atlas of all spectral features is presented. Observations of each line with a synthesized beam of ~0.9 arcsec, reveal the complex kinematics and morphology of the nebula surrounding VY CMa. Many of the molecules are observed in high lying rotational levels or in excited vibrational levels. From these, it was established that the main source of the submillimeter-wave continuum (dust) and the high excitation molecular gas (the star) are separated by about 0.15 arcsec. Apparent coincidences between the molecular gas observed with the SMA, and some of the arcs and knots observed at infrared wavelengths and in the optical scattered light by the Hubble Space Telescope are identified. The observations presented here provide important constraints on the molecular chemistry in oxygen-dominated circumstellar environments and a deeper picture of the complex circumstellar environment of VY CMa.

PO and PN in the wind of the oxygen-rich AGB star IK Tau

Phosphorus-bearing compounds have only been studied in the circumstellar environments (CSEs) of the asymptotic giant branch (AGB) star IRC +10216 and the protoplanetary nebula CRL 2688, both C-rich objects, and the O-rich red supergiant VY CMa. The current chemical models cannot reproduce the high abundances of PO and PN derived from observations of VY CMa. No observations have been reported of phosphorus in the CSEs of O-rich AGB stars. We aim to set observational constraints on the phosphorous chemistry in the CSEs of O-rich AGB stars, by focussing on the Mira-type variable star IK Tau. Using the IRAM 30m telescope and the Submillimeter Array (SMA), we observed four rotational transitions of PN (J=2-1,3-2,6-5,7-6) and four of PO (J=5/2-3/2,7/2-5/2,13/2-11/2,15/2-13/2). The IRAM 30m observations were dedicated line observations, while the SMA data come from an unbiased spectral survey in the frequency range 279-355 GHz. We present the first detections of PN and PO in an O-rich AGB star and estimate abundances X(PN/H2) of about 3x10^-7 and X(PO/H2) in the range 0.5-6.0x10^-7. This is several orders of magnitude higher than what is found for the C-rich AGB star IRC +10216. The diameter (<=0.7) of the PN and PO emission distributions measured in the interferometric data corresponds to a maximum radial extent of about 40 stellar radii. The abundances and the spatial occurrence of the molecules are in very good agreement with the results reported for VY CMa. We did not detect PS or PH3 in the survey. We suggest that PN and PO are the main carriers of phosphorus in the gas phase, with abundances possibly up to several 10^-7. The current chemical models cannot account for this, underlining the strong need for updated chemical models that include phosphorous compounds.

Dust-forming molecules in VY Canis Majoris (and Betelgeuse)

The formation of inorganic dust in circumstellar environments of evolved stars is poorly understood. Spectra of molecules thought to be most important for the nucleation, i.e. AlO, TiO, and TiO2, have been recently detected in the red supergiant VY CMa. These molecules are effectively formed in VY CMa and the observations suggest that non-equilibrium chemistry must be involved in their formation and nucleation into dust. In addition to exploring the recent observations of VY CMa, we briefly discuss the possibility of detecting these molecules in the dust-poor circumstellar environment of Betelgeuse.

Pure rotational spectra of TiO and TiO_2 in VY Canis Majoris

We report the first detection of pure rotational transitions of TiO and TiO_2 at (sub-)millimeter wavelengths towards the red supergiant VY CMa. A rotational temperature, T_rot, of about 250 K was derived for TiO_2. Although T_rot was not well constrained for TiO, it is likely somewhat higher than that of TiO_2. The detection of the Ti oxides confirms that they are formed in the circumstellar envelopes of cool oxygen-rich stars and may be the seeds of inorganic-dust formation, but alternative explanations for our observation of TiO and TiO_2 in the cooler regions of the envelope cannot be ruled out at this time. The observations suggest that a significant fraction of the oxides is not converted to dust, but instead remains in the gas phase throughout the outflow.

Aluminium oxide in the optical spectrum of VY Canis Majoris

We report the first identification of the optical bands of the B-X system of AlO in the red supergiant VY CMa. In addition to TiO, VO, ScO, and YO, which were recognized in the optical spectrum of the star long time ago, AlO is another refractory molecule which displays strong emission bands in this peculiar star. Simulating the bands of AlO, we derive a rotational temperature of the circumstellar gas of Trot=700K. By resolving individual rotational components of the bands, we derive the kinematical characteristics of the gas, finding that the emission is centered at the stellar radial velocity and its intrinsic width is 13.5 km/s (full width at half maximum). It is the narrowest emission among all (thermal) features observed in VY CMa so far. The temperature and line widths suggest that the emission arises in gas located within ~20 stellar radii, where the outflow is still being accelerated. This result contradicts equilibrium-chemistry models which predict substantial AlO abundances only to within a few stellar radii. We argue that non-equilibrium models involving propagation of shocks are needed to explain the observations.