We report on the diffuse X-ray emissions from the Galactic center (GCDX) observed with the X-ray Imaging Spectrometer (XIS) on board the Suzaku satellite. The highly accurate energy calibrations and extremely low background of the XIS provide many ne
w facts on the GCDX. These are (1) the origin of the 6.7/7.0keV lines is collisional excitation in hot plasma, (2) new SNR and super-bubble candidates are found, (3) most of the 6.4keV line is fluorescence by X-rays, and (4) time variability of the 6.4keV line is found from the SgrB2 complex.