This Letter details a measurement of the ionization yield ($Q_y$) of 6.7 keV $^{40}Ar$ atoms stopping in a liquid argon detector. The $Q_y$ of 3.6-6.3 detected $e^{-}/mbox{keV}$, for applied electric fields in the range 240--2130 V/cm, is encouraging
for the use of this detector medium to search for the signals from hypothetical dark matter particle interactions and from coherent elastic neutrino nucleus scattering. A significant dependence of $Q_y$ on the applied electric field is observed and explained in the context of ion recombination.
We describe the first demonstration of a sub-keV electron recoil energy threshold in a dual-phase liquid argon time projection chamber. This is an important step in an effort to develop a detector capable of identifying the ionization signal resultin
g from nuclear recoils with energies of order a few keV and below. We obtained this result by observing the peaks in the energy spectrum at 2.82 keV and 0.27 keV, following the K- and L-shell electron capture decay of Ar-37, respectively. The Ar-37 source preparation is described in detail, since it enables calibration that may also prove useful in dark matter direct detection experiments. An internally placed Fe-55 x-ray source simultaneously provided another calibration point at 5.9 keV. We discuss the ionization yield and electron recombination in liquid argon at those three calibration energies.
