The anisotropic nature of the new two-dimensional (2D) material phosphorene, in contrast to other 2D materials such as graphene and transition metal dichalcogenide (TMD) semiconductors, allows excitons to be confined in a quasi-one-dimensional (1D) s
pace predicted in theory, leading to remarkable phenomena arising from the reduced dimensionality and screening. Here, we report a trion (charged exciton) binding energy of 190 meV in few-layer phosphorene at room temperature, which is nearly one to two orders of magnitude larger than those in 2D TMD semiconductors (20-30 meV) and quasi-2D quantum wells (1-5 meV). Such a large binding energy has only been observed in truly 1D materials such as carbon nanotubes, whose optoelectronic applications have been severely hurdled by their intrinsically small optical cross-sections. Phosphorene offers an elegant way to overcome this hurdle by enabling quasi-1D excitonic and trionic behaviors in a large 2D area, allowing optoelectronic integration. We experimentally validated the quasi-1D nature of excitonic and trionic dynamics in phospherene by demonstrating completely linearly polarized light emission from excitons and trions. The implications of the extraordinarily large trion binding energy in a higher-than-one-dimensional material are far-reaching. It provides a room-temperature 2D platform to observe the fundamental many-body interactions in the quasi-1D region. The strong photoluminescence emission in phosphorene has been electrically tuned over a large spectral range at room temperature, which opens a new route for tunable light sources.
Negative index metamaterials (NIMs) give rise to unusual and intriguing properties and phenomena, which may lead to important applications such as superlens, subwavelength cavity and slow light devices. However, the negative refractive index in metam
aterials normally requires a stringent condition of simultaneously negative permittivity and negative permeability. A new class of negative index metamaterials - chiral NIMs, have been recently proposed. In contrast to the conventional NIMs, chiral NIMs do not require the above condition, thus presenting a very robust route toward negative refraction. Here we present the first experimental demonstration of a chiral metamaterial exhibiting negative refractive index down to n=-5 at terahertz frequencies, with only a single chiral resonance. The strong chirality present in the structure lifts the degeneracy for the two circularly polarized waves and relieves the double negativity requirement. Chiral NIM are predicted to possess intriguing electromagnetic properties that go beyond the traditional NIMs, such as opposite signs of refractive indices for the two circular polarizations and negative reflection. The realization of terahertz chiral NIMs offers new opportunities for investigations of their novel electromagnetic properties, as well as important terahertz device applications.
Frames on Hilbert C*-modules have been defined for unital C*-algebras by Frank and Larson and operator valued frames on a Hilbert space have been studied in arXiv.0707.3272v1.[math.FA]. Goal of the present paper is to introduce operator valued frames
on a Hilbert C*-module for a sigma-unital C*-algebra. Theorem 1.4 reformulates the definition given by Frank and Larson in terms of a series of rank-one operators converging in the strict topology. Theorem 2.2. shows that the frame transform and the frame projection of an operator valued frame are limits in the strict topology of a series of elements in the multiplier algebra and hence belong to it. Theorem 3.3 shows that two operator valued frames are right similar if and only if they share the same frame projection. Theorem 3.4 establishes a one to one correspondence between Murray-von Neumann equivalence classes of projections in the multiplier algebra and right similarity equivalence classes of operator valued frames and provides a parametrization of all Parseval operator-valued frames on a given Hilbert C*-module. Left similarity is then defined and Proposition 3.9 establishes when two left unitarily equivalent frames are also right unitarily equivalent.
We develop a natural generalization of vector-valued frame theory, we term operator-valued frame theory, using operator-algebraic methods. This extends work of the second author and D. Han which can be viewed as the multiplicity one case and extends
to higher multiplicity (e.g., multiframes) their dilation approach. We prove several results for operator-valued frames concerning their parametrization, duality, disjointeness, complementarity, and composition and the relationship between the two types of similarity (left and right) of such frames. We then apply these notions to prove that the collection of multiframe generators for the action of a discrete group on a Hilbert space is norm pathwise-connected precisely when the von Neumann algebra generated by the right representation of the group has no minimal projections. The proof is obtained by parametrizing this collection by a class of partial isometries in a larger von Neumann algebra. In the multiplicity one case this class reduces to the unitary class which is path-connected in norm, but in the infinite multiplicity case this class is path connected only in the strong operator topology and the proof depends on properties of tensor product slice maps.
