We imaged two starless molecular cloud cores, TUKH083 and TUKH122, in the Orion A giant molecular cloud in the CCS and ammonia (NH$_3$) emission with the Very Large Array. TUKH122 contains one NH$_3$ core TUKH122-n, which is elongated and has a smoot
h oval boundary. Where observed, the CCS emission surrounds the NH$_3$ core. This configuration resembles that of the N$_2$H$^+$ and CCS distribution in the Taurus starless core L1544, a well-studied example of a dense prestellar core exhibiting infall motions. The linewidth of TUKH122-n is narrow (0.20 km s$^{-1}$) in the NH$_3$ emission line and therefore dominated by thermal motions. The smooth oval shape of the core boundary and narrow linewidth in NH$_3$ seem to imply that TUKH122-n is dynamically relaxed and quiescent. TUKH122-n is similar to L1544 in the kinetic temperature (10 K), linear size (0.03 pc), and virial mass ($sim$ 2 $M_{odot}$). Our results strongly suggest that TUKH122-n is on the verge of star formation. TUKH122-n is embedded in the 0.2 pc massive (virial mass $sim$ 30 $M_{odot}$) turbulent parent core, while the L1544 NH$_3$ core is embedded in the 0.2 pc less-massive (virial mass $sim$ 10 $M_{odot}$) thermal parent core. TUKH083 shows complicated distribution in NH$_3$, but was not detected in CCS. The CCS emission toward TUKH083 appears to be extended, and is resolved out in our interferometric observations.
We have mapped six molecular cloud cores in the Orion A giant molecular cloud (GMC), whose kinetic temperatures range from 10 to 30 K, in CCS and N2H+ with Nobeyama 45 m radio telescope to study their chemical characteristics. We identified 31 intens
ity peaks in the CCS and N2H+ emission in these molecular cloud cores. It is found for cores with temperatures lower than ~ 25 K that the column density ratio of N(N2H+)/N(CCS) is low toward starless core regions while it is high toward star-forming core regions, in case that we detected both of the CCS and N2H+ emission. This is very similar to the tendency found in dark clouds (kinetic temperature ~ 10 K). The criterion found in the Orion A GMC is N(N2H+)/N(CCS) ~ 2-3. In some cases, the CCS emission is detected toward protostars as well as the N2H+ emission. Secondary late-stage CCS peak in the chemical evolution caused by CO depletion may be a possible explanation for this. We found that the chemical variation of CCS and N2H+ can also be used as a tracer of evolution in warm (10-25 K) GMC cores. On the other hand, some protostars do not accompany N2H+ intensity peaks but are associated with dust continuum emitting regions, suggesting that the N2H+ abundance might be decreased due to CO evaporation in warmer star-forming sites.
