Phase transition from anatase to rutile for the 70nm TiO2 crystallite has been investigated by annealing at different temperatures followed by TDPAC measurement of these TiO2 crystallites adsorbed with 181Hf tracer. The width of the peaks in XRD spec
tra for TiO2 crystallites annealed at different temperatures indicates the growth of the crystallites with temperature. The samples annealed upto 823K for 4hrs showed no phase transition, except the growth of the crystallites. However, it showed phase transition at the same temperature (823K), when annealed for longer duration. Annealing for shorter duration at 1123K showed phase transition. 181Hf tracer adsorbed on 70 nm anatase TiO2 is found to be in different polymorphs (anatase & rutile) formed during annealing process. Surface to bulk mass-transfer is found to play a significant role in the phase transition process.
