How Interstellar Chemistry (and Astrochemistry More Generally) Became Useful

In 1986 Alex Dalgarno published a paper entitled Is Interstellar Chemistry Useful? By the middle 1970s, and perhaps even earlier, Alex had hoped that astronomical molecules would prove to: possess significant diagnostic utility; control many of the environments in which they exist; stimulate a wide variety of physicists and chemists who are at least as fascinated by the mechanisms forming and removing the molecules as by astronomy. His own research efforts have contributed greatly to the realization of that hope. This paper contains a few examples of: how molecules are used to diagnose large-scale dynamics in astronomical sources including star forming regions and supernovae; the ways in which molecular processes control the evolution of astronomical objects such as dense cores destined to become stars and very evolved giant stars; theoretical and laboratory investigations that elucidate the processes producing and removing astronomical molecules and allow their detection.

Dust in Interstellar Clouds, Evolved Stars and Supernovae

Outflows of pre-main-sequence stars drive shocks into molecular material within 0.01 - 1 pc of the young stars. The shock-heated gas emits infrared, millimeter and submillimeter lines of many species including. Dust grains are important charge carriers and play a large role in coupling the magnetic field and flow of neutral gas. Some effects of the dust on the dynamics of oblique shocks began to emerge in the 1990s. However, detailed models of these shocks are required for the calculation of the grain sputtering contribution to gas phase abundances of species producing observed emissions. We are developing such models. Some of the molecular species introduced into the gas phase by sputtering in shocks or by thermally driven desorption in hot cores form on grain surfaces. Recently laboratory studies have begun to contribute to the understanding of surface reactions and thermally driven desorption important for the chemistry of star forming clouds. Dusty plasmas are prevalent in many evolved stars just as well as in star forming regions. Radiation pressure on dust plays a significant role in mass loss from some post-main-sequence stars. The mechanisms leading to the formation of carbonaceous dust in the stellar outflows are similar to those important for soot formation in flames. However, nucleation in oxygen-rich outflows is less well understood and remains a challenging research area. Dust is observed in supernova ejecta that have not passed through the reverse shocks that develop in the interaction of ejecta with ambient media. Dust is detected in high redshift galaxies that are sufficiently young that the only stars that could have produced the dust were so massive that they became supernovae. Consequently, the issue of the survival of dust in strong supernova shocks is of considerable interest.

The effect of ambipolar resistivity on the formation of dense cores

We aim to understand the formation of dense cores by magnetosonic waves in regions where the thermal to magnetic pressure ratio is small. Because of the low-ionisation fraction in molecular clouds, neutral and charged particles are weakly coupled. Ambipolar diffusion then plays an important role in the formation process. A quiescent, uniform plasma is perturbed by a fast-mode wave. Using 2D numerical simulations, we follow the evolution of the fast-mode wave. The simulations are done with a multifluid, adaptive mesh refinement MHD code. Initial perturbations with wavelengths that are 2 orders of magnitude larger than the dissipation length are strongly affected by the ion-neutral drift. Only in situations where there are large variations in the magnetic field corresponding to a highly turbulent gas can fast-mode waves generate dense cores. This means that, in most cores, no substructure can be produced. However, Core D of TMC-1 is an exception to this case. Due to its atypically high ionisation fraction, waves with wavelengths up to 3 orders of magnitude greater than the dissipation length can be present. Such waves are only weakly affected by ambipolar diffusion and can produce dense substructure without large wave-amplitudes. Our results also explain the observed transition from Alfvenic turbulent motion at large scales to subsonic motions at the level of dense cores.

Non-thermal radio emission from O-type stars III. Is Cyg OB2 No. 9 a wind-colliding binary?

The star Cyg OB2 No. 9 is a well-known non-thermal radio emitter. Recent theoretical work suggests that all such O-stars should be in a binary or a multiple system. However, there is no spectroscopic evidence of a binary component. Re-analysis of radio observations from the VLA of this system over 25 years has revealed that the non-thermal emission varies with a period of 2.35+-0.02 yr. This is interpreted as a strong suggestion of a binary system, with the non-thermal emission arising in a wind-collision region. We derived some preliminary orbital parameters for this putative binary and revised the mass-loss rate of the primary star downward from previous estimates.

Shock-triggered formation of magnetically-dominated clouds

To understand the formation of a magnetically dominated molecular cloud out of an atomic cloud, we follow the dynamical evolution of the cloud with a time-dependent axisymmetric magnetohydrodynamic code. A thermally stable warm atomic cloud is initially in static equilibrium with the surrounding hot ionised gas. A shock propagating through the hot medium interacts with the cloud. As a fast-mode shock propagates through the cloud, the gas behind it becomes thermally unstable. The $beta$ value of the gas also becomes much smaller than the initial value of order unity. These conditions are ideal for magnetohydrodynamic waves to produce high-density clumps embedded in a rarefied warm medium. A slow-mode shock follows the fast-mode shock. Behind this shock a dense shell forms, which subsequently fragments. This is a primary region for the formation of massive stars. Our simulations show that only weak and moderate-strength shocks can form cold clouds which have properties typical of giant molecular clouds.