We have prepared oxygen isotope exchanged crystals of impurity-free YBCO with various oxygen concentents, and examined pure doping ($p$) dependance of isotope effect on superconducting transition temperature. With decreasing oxygen contents, the isot
ope exponent $alpha$ monotonously increases without any anomaly around $p = 1/8$. The monotonous increase in $alpha$ indicates that phonons are involved in the mechanism which causes the monotonous $T_c$ suppression with underdoping.
Electronic anisotropy was studied for overdoped (Y,Ca)Ba2Cu3O7-d with various doping levels (p). It was found that the pseudogap-like behavior in the resistivity disappear when p exceeds 0.17, independent of the oxygen deficiency. The anisotropy rati
o (g) estimated from upper critical fields showed a rapid decrease at around p = 0.18, approaching g = 3 for p > 0.20.
We report Raman scattering spectra for single crystals of overdoped Tl2Ba2CuO6+d (Tl-2201) at low temperatures. It was observed that the pair-breaking peaks in A1g and B1g spectra radically shift to lower energy with carrier doping. We interpret it a
s s-wave component mixing into d-wave, although the crystal structure is tetragonal. Since similar phenomena were observed also in YBa2Cu3Oy and Bi2Sr2CaCu2Oz, we conclude that s-wave mixing is a common property for overdoped high-Tc superconductors.
