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We have performed a low temperature scanning tunneling microscopy and spectroscopy study of the iron chalcogenide superconductor FeSe_{0.4}Te_{0.6} with T_{C}~14 K. Spatially resolved measurements of the superconducting gap reveal substantial inhomog eneity on a nanometer length scale. Analysis of the structure of the gap seen in tunneling spectra by comparison with calculated spectra for different superconducting order parameters (s-wave, d-wave, and anisotropic s-wave) yields the best agreement for an order parameter with anisotropic s-wave symmetry with an anisotropy of ~40%. The temperature dependence of the superconducting gap observed in places with large and small gap size indicates that it is indeed the superconducting transition temperature which is inhomogeneous. The temperature dependence of the gap size is substantially larger than would be expected from BCS theory. An analysis of the local gap size in relation with the local chemical composition shows almost no correlation with the local concentration of Se-/Te-atoms at the surface.
We calculate the nonlinear cotunneling conductance through a quantum dot with 3 electrons occupying the three highest lying energy levels. Starting from a 3-orbital Anderson model, we apply a generalized Schrieffer-Wolff transformation to derive an e ffective Kondo model for the system. Within this model we calculate the nonequilibrium occupation numbers and the corresponding cotunneling current to leading order in the exchange couplings. We identify the inelastic cotunneling thresholds and their splittings with applied magnetic field, and make a qualitative comparison to recent experimental data on carbon nanotube and InAs quantum-wire quantum dots. Further predictions of the model like cascade resonances and a magnetic-field dependence of the orbital level splitting are not yet observed but within reach of recent experimental work on carbon nanotube and InAs nanowire quantum dots.
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