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In the absence of magnetic fields and cosmic rays, radiative cooling laws with a range of dependences on temperature affect the stability of interstellar gas. For about four and a half decades, astrophysicists have recognised the importance of the th ermal instablity for the formation of clouds in the interstellar medium. Even in the past several years, many papers have concerned the role of the thermal instability in the production of molecular clouds. About three and a half decades ago, astrophysicists investigating radiative shocks noticed that for many cooling laws such shocks are unstable. Attempts to address the effects of cosmic rays on the stablity of radiative media that are initially uniform or that have just passed through shocks have been made. The simplest approach to such studies involves the assumption that the cosmic rays behave as a fluid. Work based on such an approach is described. Cosmic rays have no effect on the stability of initially uniform, static media with respect to isobaric perturbations, though they do affect the stability of such media with respect to isentropic perturbations. The effect of cosmic rays on the stability of radiative shocked media depends greatly on the efficiency of the conversion of energy in accelerated cosmic rays into thermal energy in the thermalized fluid. If that efficiency is low, radiative cooling makes weak shocks propagating into upstream media with low cosmic-ray pressures more likely to be cosmic-ray dominated than adiabatic shocks of comparable strength. The cosmic-ray dominated shocks do not display radiative overstability. Highly efficient conversion of cosmic-ray energy into thermal energy leads shocked media to behave as they do when cosmic rays are absent.
In 1986 Alex Dalgarno published a paper entitled Is Interstellar Chemistry Useful? By the middle 1970s, and perhaps even earlier, Alex had hoped that astronomical molecules would prove to: possess significant diagnostic utility; control many of the e nvironments in which they exist; stimulate a wide variety of physicists and chemists who are at least as fascinated by the mechanisms forming and removing the molecules as by astronomy. His own research efforts have contributed greatly to the realization of that hope. This paper contains a few examples of: how molecules are used to diagnose large-scale dynamics in astronomical sources including star forming regions and supernovae; the ways in which molecular processes control the evolution of astronomical objects such as dense cores destined to become stars and very evolved giant stars; theoretical and laboratory investigations that elucidate the processes producing and removing astronomical molecules and allow their detection.
Outflows of pre-main-sequence stars drive shocks into molecular material within 0.01 - 1 pc of the young stars. The shock-heated gas emits infrared, millimeter and submillimeter lines of many species including. Dust grains are important charge carrie rs and play a large role in coupling the magnetic field and flow of neutral gas. Some effects of the dust on the dynamics of oblique shocks began to emerge in the 1990s. However, detailed models of these shocks are required for the calculation of the grain sputtering contribution to gas phase abundances of species producing observed emissions. We are developing such models. Some of the molecular species introduced into the gas phase by sputtering in shocks or by thermally driven desorption in hot cores form on grain surfaces. Recently laboratory studies have begun to contribute to the understanding of surface reactions and thermally driven desorption important for the chemistry of star forming clouds. Dusty plasmas are prevalent in many evolved stars just as well as in star forming regions. Radiation pressure on dust plays a significant role in mass loss from some post-main-sequence stars. The mechanisms leading to the formation of carbonaceous dust in the stellar outflows are similar to those important for soot formation in flames. However, nucleation in oxygen-rich outflows is less well understood and remains a challenging research area. Dust is observed in supernova ejecta that have not passed through the reverse shocks that develop in the interaction of ejecta with ambient media. Dust is detected in high redshift galaxies that are sufficiently young that the only stars that could have produced the dust were so massive that they became supernovae. Consequently, the issue of the survival of dust in strong supernova shocks is of considerable interest.
We aim to understand the formation of dense cores by magnetosonic waves in regions where the thermal to magnetic pressure ratio is small. Because of the low-ionisation fraction in molecular clouds, neutral and charged particles are weakly coupled. Am bipolar diffusion then plays an important role in the formation process. A quiescent, uniform plasma is perturbed by a fast-mode wave. Using 2D numerical simulations, we follow the evolution of the fast-mode wave. The simulations are done with a multifluid, adaptive mesh refinement MHD code. Initial perturbations with wavelengths that are 2 orders of magnitude larger than the dissipation length are strongly affected by the ion-neutral drift. Only in situations where there are large variations in the magnetic field corresponding to a highly turbulent gas can fast-mode waves generate dense cores. This means that, in most cores, no substructure can be produced. However, Core D of TMC-1 is an exception to this case. Due to its atypically high ionisation fraction, waves with wavelengths up to 3 orders of magnitude greater than the dissipation length can be present. Such waves are only weakly affected by ambipolar diffusion and can produce dense substructure without large wave-amplitudes. Our results also explain the observed transition from Alfvenic turbulent motion at large scales to subsonic motions at the level of dense cores.
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