Aims: Accretion rates in low-mass protostars can be highly variable in time. Each accretion burst is accompanied by a temporary increase in luminosity, heating up the circumstellar envelope and altering the chemical composition of the gas and dust. T
his paper aims to study such chemical effects and discusses the feasibility of using molecular spectroscopy as a tracer of episodic accretion rates and timescales. Methods: We simulate a strong accretion burst in a diverse sample of 25 spherical envelope models by increasing the luminosity to 100 times the observed value. Using a comprehensive gas-grain network, we follow the chemical evolution during the burst and for up to 10^5 yr after the system returns to quiescence. The resulting abundance profiles are fed into a line radiative transfer code to simulate rotational spectra of C18O, HCO+, H13CO+, and N2H+ at a series of time steps. We compare these spectra to observations taken from the literature and to previously unpublished data of HCO+ and N2H+ 6-5 from the Herschel Space Observatory. Results: The bursts are strong enough to evaporate CO throughout the envelope, which in turn enhances the abundance of HCO+ and reduces that of N2H+. After the burst, it takes 10^3-10^4 yr for CO to refreeze and for HCO+ and N2H+ to return to normal. The chemical effects of the burst remain visible in the rotational spectra for as long as 10^5 yr after the burst has ended, highlighting the importance of considering luminosity variations when analyzing molecular line observations in protostars. The spherical models are currently not accurate enough to derive robust timescales from single-dish observations. As follow-up work, we suggest that the models be calibrated against spatially resolved observations in order to identify the best tracers to be used for statistically significant source samples.
(Abridged) Star and planet formation theories predict an evolution in the density, temperature, and velocity structure as the envelope collapses and forms an accretion disk. The aim of this work is to model the evolution of the molecular excitation,
line profiles, and related observables during low-mass star formation. Specifically, the signatures of disks during the deeply embedded stage are investigated. Semi-analytic 2D axisymmetric models have been used to describe the evolution of the density, stellar mass, and luminosity from the pre-stellar to the T-Tauri phase. A full radiative transfer calculation is carried out to accurately determine the time-dependent dust temperatures and CO abundance structure. We present non-LTE near-IR, FIR, and submm lines of CO have been simulated at a number of time steps. In contrast to the dust temperature, the CO excitation temperature derived from submm/FIR lines does not vary during the protostellar evolution, consistent with C18O observations obtained with Herschel and from ground-based telescopes. The near-IR spectra provide complementary information to the submm lines by probing not only the cold outer envelope but also the warm inner region. The near-IR high-J (>8) absorption lines are particularly sensitive to the physical structure of the inner few AU, which does show evolution. High signal-to-noise ratio subarcsec resolution data with ALMA are needed to detect the presence of small rotationally supported disks during the Stage 0 phase and various diagnostics are discussed.
Evaporation of water ice above 100 K in the inner few 100 AU of low-mass embedded protostars (the so-called hot core) should produce quiescent water vapor abundances of ~10^-4 relative to H2. Observational evidence so far points at abundances of only
a few 10^-6. However, these values are based on spherical models, which are known from interferometric studies to be inaccurate on the relevant spatial scales. Are hot cores really that much drier than expected, or are the low abundances an artifact of the inaccurate physical models? We present deep velocity-resolved Herschel-HIFI spectra of the 3(12)-3(03) lines of H2-16O and H2-18O (1097 GHz, Eup/k = 249 K) in the low-mass Class 0 protostar NGC1333 IRAS2A. A spherical radiative transfer model with a power-law density profile is unable to reproduce both the HIFI data and existing interferometric data on the H2-18O 3(13)-2(20) line (203 GHz, Eup/k = 204 K). Instead, the HIFI spectra likely show optically thick emission from a hot core with a radius of about 100 AU. The mass of the hot core is estimated from the C18O J=9-8 and 10-9 lines. We derive a lower limit to the hot water abundance of 2x10^-5, consistent with the theoretical predictions of ~10^-4. The revised HDO/H2O abundance ratio is 1x10^-3, an order of magnitude lower than previously estimated.
We explore a set of single-point chemical models to study the fundamental chemical aspects of episodic accretion in low-mass embedded protostars. Our goal is twofold: (1) to understand how the repeated heating and cooling of the envelope affects the
abundances of CO and related species; and (2) to identify chemical tracers that can be used as a novel probe of the timescales and other physical aspects of episodic accretion. We develop a set of single-point models that serve as a general prescription for how the chemical composition of a protostellar envelope is altered by episodic accretion. The main effect of each accretion burst is to drive CO ice off the grains in part of the envelope. The duration of the subsequent quiescent stage (before the next burst hits) is similar to or shorter than the freeze-out timescale of CO, allowing the chemical effects of a burst to linger long after the burst has ended. We predict that the resulting excess of gas-phase CO can be observed with single-dish or interferometer facilities as evidence of an accretion burst in the past 10^3 - 10^4 yr.
Photodissociation is the dominant removal process of molecules in any region exposed to intense ultraviolet (UV) radiation. This includes diffuse and translucent interstellar clouds, dense photon-dominated regions, high velocity shocks, the surface l
ayers of protoplanetary disks, and cometary and exoplanetary atmospheres. The rate of photodissociation depends on the cross sections for absorption into a range of excited electronic states, as well as on the intensity and shape of the radiation field at each position into the region of interest. Thus, an acccurate determination of the photodissociation rate of even a simple molecule like water or carbon monoxide involves many detailed considerations ranging from its electronic structure to its dissociation dynamics and the specifics of the radiation field that the molecule is exposed to. In this review chapter, each of these steps in determining photodissociation rates is discussed systematically and examples are provided.
