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The derivation of Lorentz-covariant generalizations of Ohms law has been a long-term issue in theoretical physics with deep implications for the study of relativistic effects in optical and atomic physics. In this article, we propose an alternative r oute to this problem, which is motivated by the tremendous progress in first-principles materials physics in general and ab initio electronic structure theory in particular. We start from the most general, Lorentz-covariant first-order response law, which is written in terms of the fundamental response tensor $chi^mu_ u$ relating induced four-currents to external four-potentials. By showing the equivalence of this description to Ohms law, we prove the validity of Ohms law in every inertial frame. We further use the universal relation between $chi^mu_ u$ and the microscopic conductivity tensor $sigma_{kell}$ to derive a fully relativistic transformation law for the latter, which includes all effects of anisotropy and relativistic retardation. In the special case of a constant, scalar conductivity, this transformation law can be used to rederive a standard textbook generalization of Ohms law.
In this article, we put forward a new approach to electrodynamics of materials. Based on the identification of induced electromagnetic fields as the microscopic counterparts of polarization and magnetization, we systematically employ the mutual funct ional dependencies of induced, external and total field quantities. This allows for a unified, relativistic description of the electromagnetic response without assuming the material to be composed of electric or magnetic dipoles. Using this approach, we derive universal (material-independent) relations between electromagnetic response functions such as the dielectric tensor, the magnetic susceptibility and the microscopic conductivity tensor. Our formulae can be reduced to well-known identities in special cases, but more generally include the effects of inhomogeneity, anisotropy, magnetoelectric coupling and relativistic retardation. If combined with the Kubo formalism, they would also lend themselves to the ab initio calculation of all linear electromagnetic response functions.
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