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The magnetic properties of the molecular cluster Mn12Ac are due to the four Mn3+ ions which have spins S=3/2 and the eight Mn4+ ions with spins S=2. These spins are coupled by superexchange mechanism. We determine the four exchange couplings assuming a Heisenberg-type interaction between the ions. We use exact diagonalization of the spin Hamiltonian by a Lanczos algorithm and we adjust the couplings to reproduce the magnetization curve of Mn12Ac. We also impose the constraint of reproducing a gap of 35K between a S=10 ground state and a first excited state with S=9. We predict that there is an excited level with S=8 at 37K above the ground state, only slightly above the S=9 excited state which lies at 35K and the next excited state is a S=9 multiplet at 67K above the S=10 ground state.
105 - A. Cornia , R. Sessoli , L. Sorace 2001
The problem of the role of transverse fields in Mn12-acetate, a molecular nanomagnet, is still open. We present structural evidences that the disorder of the acetic acid of crystallization indices sizeable distortion of the Mn(III) sites, giving rise to six different isomers, four of them with symmetry lower than tetragonal. Using a ligand field approach the effect of the structure modifications on the second order transverse magnetic anisotropy, forbidden in tetragonal symmetry, has been evaluated. The order of magnitude of the quadratic transverse anisotropies well agree with the values derived by the analysis of the field sweep dependence of the hysteresis loops performed by Mertes et al. (Phys. Rev. Lett 87, 227205 (2001)) and allows to better simulate the EPR spectra.
The Landau Zener method allows to measure very small tunnel splittings Delta in molecular clusters Fe_8. The observed oscillations of Delta as a function of the magnetic field applied along the hard anisotropy axis are explained in terms of topologic al quantum interference of two tunnel paths of opposite windings. Studies of the temperature dependence of the Landau Zener transition rate P gives access to the topological quantum interference between exited spin levels. The influence of nuclear spins is demonstrated by comparing P of the standard Fe_8 sample with two isotopically substituted samples. The need of a generalized Landau Zener transition rate theory is shown.
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