Osculating paths are sets of directed lattice paths which are not allowed to cross each other or have common edges, but are allowed to have common vertices. In this work we derive a constant term formula for the number of such lattice paths by solving a set of simultaneous difference equations.
We prove a constant term theorem which is useful for finding weight polynomials for Ballot/Motzkin paths in a strip with a fixed number of arbitrary `decorated weights as well as an arbitrary `background weight. Our CT theorem, like Viennots lattice
path theorem from which it is derived primarily by a change of variable lemma, is expressed in terms of orthogonal polynomials which in our applications of interest often turn out to be non-classical. Hence we also present an efficient method for finding explicit closed form polynomial expressions for these non-classical orthogonal polynomials. Our method for finding the closed form polynomial expressions relies on simple combinatorial manipulations of Viennots diagrammatic representation for orthogonal polynomials. In the course of the paper we also provide a new proof of Viennots original orthogonal polynomial lattice path theorem. The new proof is of interest because it uses diagonalization of the transfer matrix, but gets around difficulties that have arisen in past attempts to use this approach. In particular we show how to sum over a set of implicitly defined zeros of a given orthogonal polynomial, either by using properties of residues or by using partial fractions. We conclude by applying the method to two lattice path problems important in the study of polymer physics as models of steric stabilization and sensitized flocculation.
We consider a directed walk model of a homopolymer (in two dimensions) which is self-interacting and can undergo a collapse transition, subject to an applied tensile force. We review and interpret all the results already in the literature concerning
the case where this force is in the preferred direction of the walk. We consider the force extension curves at different temperatures as well as the critical-force temperature curve. We demonstrate that this model can be analysed rigorously for all key quantities of interest even when there may not be explicit expressions for these quantities available. We show which of the techniques available can be extended to the full model, where the force has components in the preferred direction and the direction perpendicular to this. Whilst the solution of the generating function is available, its analysis is far more complicated and not all the rigorous techniques are available. However, many results can be extracted including the location of the critical point which gives the general critical-force temperature curve. Lastly, we generalise the model to a three-dimensional analogue and show that several key properties can be analysed if the force is restricted to the plane of preferred directions.
