We examine the chemical and emission properties of mildly irradiated (G0=1) magnetised shocks in diffuse media (nH=10^2 to 10^4 /cm3) at low to moderate velocities (from 3 to 40 km/s). Results: The formation of some molecules relies on endoergic reac
tions. In J-shocks, their abundances are enhanced by several orders of magnitude for shock velocities as low as 7 km/s. Otherwise most chemical properties of J-type shocks vary over less than an order of magnitude between velocities from about 7 to about 30 km/s, where H2 dissociation sets in. C-type shocks display a more gradual molecular enhancement as the shock velocity increases. We quantify the energy flux budget (fluxes of kinetic, radiated and magnetic energies) with emphasis on the main cooling lines of the cold interstellar medium. Their sensitivity to shock velocity is such that it allows observations to constrain statistical distributions of shock velocities. We fit various probability distribution functions (PDFs) of shock velocities to spectroscopic observations of the galaxy-wide shock in Stephans Quintet (SQ) and of a Galactic line of sight sampling diffuse molecular gas in Chamaeleon. In both cases, low velocities bear the greatest statistical weight and the PDF is consistent with a bimodal distribution. In the very low velocity shocks (below 5 km/s), dissipation is due to ion-neutral friction which powers H2 low energy transitions and atomic lines. In moderate velocity shocks (20 km/s and above), the dissipation is due to viscous heating and accounts for most of the molecular emission. In our interpretation a significant fraction of the gas on the line of sight is shocked (from 4% to 66%). For example, C+ emission may trace shocks in UV irradiated gas where C+ is the dominant carbon species.
Interstellar dark clouds are the sites of star formation. Their main component, dihydrogen, exists under two states, ortho and para. H2 is supposed to form in the ortho:para ratio (OPR) of 3:1 and to subsequently decay to almost pure para-H2 (OPR <=
0.001). Only if the H2 OPR is low enough, will deuteration enrichment, as observed in the cores of these clouds, be efficient. The second condition for strong deuteration enrichment is the local disappearance of CO, which freezes out onto grains in the core formation process. We show that this latter condition does not apply to DCO+, which, therefore, should be present all over the cloud. We find that an OPR >= 0.1 is necessary to prevent DCO+ large-scale apparition. We conclude that the inevitable decay of ortho-H2 sets an upper limit of ~6 million years to the age of starless molecular clouds under usual conditions.
