Nitrogen is the fifth most abundant element in the Universe, yet the gas-phase chemistry of N-bearing species remains poorly understood. Nitrogen hydrides are key molecules of nitrogen chemistry. Their abundance ratios place strong constraints on the
production pathways and reaction rates of nitrogen-bearing molecules. We observed the class 0 protostar IRAS16293-2422 with the heterodyne instrument HIFI, covering most of the frequency range from 0.48 to 1.78~THz at high spectral resolution. The hyperfine structure of the amidogen radical o-NH2 is resolved and seen in absorption against the continuum of the protostar. Several transitions of ammonia from 1.2 to 1.8~THz are also seen in absorption. These lines trace the low-density envelope of the protostar. Column densities and abundances are estimated for each hydride. We find that NH:NH2:NH3=5:1:300. {Dark clouds chemical models predict steady-state abundances of NH2 and NH3 in reasonable agreement with the present observations, whilst that of NH is underpredicted by more than one order of magnitude, even using updated kinetic rates. Additional modelling of the nitrogen gas-phase chemistry in dark-cloud conditions is necessary before having recourse to heterogen processes.
Guided by the duality of turbulence (random versus coherent we seek coherent structures in the turbulent velocity field of molecular clouds, anticipating their importance in cloud evolution. We analyse a large map (40 by 20) obtained with the HERA mu
ltibeam receiver (IRAM-30m telescope) in a high latitude cloud of the Polaris Flare at an unprecedented spatial (11) and spectral (0.05 km/s) resolutions in the 12CO(2-1) line. We find that two parsec-scale components of velocities differing by ~2 km/s, share a narrow interface ($<0.15$ pc) that appears as an elongated structure of intense velocity-shear, ~15 to 30 km/s/pc. The locus of the extrema of line--centroid-velocity increments (E-CVI) in that field follows this intense-shear structure as well as that of the 12CO(2-1) high-velocity line wings. The tiny spatial overlap in projection of the two parsec-scale components implies that they are sheets of CO emission and that discontinuities in the gas properties (CO enrichment and/or increase of gas density) occur at the position of the intense velocity shear. These results disclose spatial and kinematic coherence between scales as small as 0.03 pc and parsec scales. They confirm that the departure from Gaussianity of the probability density functions of E-CVIs is a powerful statistical tracer of the intermittency of turbulence. They disclose a link between large scale turbulence, its intermittent dissipation rate and low-mass dense core formation.
We further characterize the structures tentatively identified on thermal and chemical grounds as the sites of dissipation of turbulence in molecular clouds (Papers I and II). Our study is based on two-point statistics of line centroid velocities (CV)
, computed from three large 12CO maps of two fields. Probability density functions (PDF) of the CO line centroid velocity increments (CVI) over lags varying by an order of magnitude and structure functions of the line CV, up to the 6th order, are computed. We show that the line CV bear the three signatures of intermittency in a turbulent velocity field: (1) the non-Gaussian tails in the CVI PDF grow as the lag decreases, (2) the departure from Kolmogorov scaling of the high-order structure functions is more pronounced in the more turbulent field, (3) the positions contributing to the CVI PDF tails delineate narrow filamentary structures (thickness ~ 0.02 pc), uncorrelated to dense gas structures and spatially coherent with thicker ones (~0.18 pc) observed on larger scales. The confrontation with theoretical predictions leads us to identify these small-scale filamentary structures with extrema of velocity-shears associated with gas warmer than the bulk. Last, their average direction is parallel (or close) to that of the local magnetic field projection. Turbulence in these translucent fields exhibits the statistical and structural signatures of small-scale and inertial-range intermittency. The more turbulent field on the 30 pc-scale is also the more intermittent on small scales. The small-scale intermittent structures coincide with those formerly identified as sites of enhanced dissipation. They are organized into parsec-scale coherent structures, coupling a broad range of scales.
Determining the structure of and the velocity field in prestellar cores is essential to understanding protostellar evolution.} {We have observed the dense prestellar cores L 1544 and L 183 in the $N = 1 to 0$ rotational transition of CN and thcn in o
rder to test whether CN is depleted in the high--density nuclei of these cores.} {We have used the IRAM 30 m telescope to observe along the major and minor axes of these cores. We compare these observations with the 1 mm dust emission, which serves as a proxy for the hydrogen column density.}{We find that while CNjone is optically thick, the distribution of thcnjone intensity follows the dust emission well, implying that the CN abundance does not vary greatly with density. We derive an abundance ratio of $rm [CN]/[hh]=dix{-9}$ in L 183 and 1-3tdix{-9} in L 1544, which, in the case of L 183, is similar to previous estimates obtained by sampling lower--density regions of the core.}{We conclude that CN is not depleted towards the high--density peaks of these cores and thus behaves like the N-containing molecules nhp and hhh. CN is, to our knowledge, the first C--containing molecule to exhibit this characteristic.
