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We show that the quasi-skutterudite superconductor Sr_3Ir_4Sn_{13} undergoes a structural transition from a simple cubic parent structure, the I-phase, to a superlattice variant, the I-phase, which has a lattice parameter twice that of the high tempe rature phase. We argue that the superlattice distortion is associated with a charge density wave transition of the conduction electron system and demonstrate that the superlattice transition temperature T* can be suppressed to zero by combining chemical and physical pressure. This enables the first comprehensive investigation of a superlattice quantum phase transition and its interplay with superconductivity in a cubic charge density wave system.
We report high pressure magnetic susceptibility and electrical resistivity measurements on Ca_{3}Ir_{4}Sn_{13} single crystals up to 60 kbar. These measurements allow us to follow the evolution of the superconducting critical temperature T_c, the res istivity anomaly temperature T*, the superconducting coherence length and the Fermi velocity under pressure. The pressure-temperature phase diagram constructed for Ca_{3}Ir_{4}Sn_{13} shows a dome-shaped pressure dependence of T_c. The initial rise in T_c, which is accompanied by a decrease in T*, is consistent with a reduction in the partial gapping of the Fermi surface under pressure.
The layered perovskite Ca2RuO4 is a spin-one Mott insulator at ambient pressure and exhibits metallic ferromagnetism at least up to ~ 80 kbar with a maximum Curie temperature of 28 K. Above ~ 90 kbar and up to 140 kbar, the highest pressure reached, the resistivity and ac susceptibility show pronounced downturns below ~ 0.4 K in applied magnetic fields of up to ~10 mT. This indicates that our specimens of Ca2RuO4 are weakly superconducting on the border of a quasi-2D ferromagnetic state.
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