Distinctive rings in the 21 cm signal of the epoch of reionization

It is predicted that sources emitting UV radiation in the Lyman band during the epoch of reionization (EoR) showed a series of discontinuities in their Ly-alpha flux radial profile as a consequence of the thickness of the Lyman line series in the primeval intergalactic medium. Through unsaturated Wouthuysen-Field coupling, these spherical discontinuities are also present in the 21 cm emission of the neutral IGM. In this article, we study the effects these discontinuities have on the differential brightness temperature of the 21 cm signal of neutral hydrogen in a realistic setting including all other sources of fluctuations. We focus on the early phases of the EoR, and we address the question of the detectability by the planned Square Kilometre Array. Such a detection would be of great interest, because these structures could provide an unambiguous diagnostic for the cosmological origin of the signal remaining after the foreground cleaning procedure. Also, they could be used as a new type of standard rulers. We determine the differential brightness temperature of the 21 cm signal in the presence of inhomogeneous Wouthuysen-Field effect using simulations which include (hydro)dynamics and both ionizing and Lyman lines 3D radiative transfer with the code LICORICE. We find that the Lyman horizons are clearly visible on the maps and radial profiles around the first sources of our simulations, but for a limited time interval, typically Delta z approx 2 at z sim 13. Stacking the profiles of the different sources of the simulation at a given redshift results in extending this interval to Delta z approx 4. When we take into account the implementation and design planned for the SKA (collecting area, sensitivity, resolution), we find that detection will be challenging. It may be possible with a 10 km diameter for the core, but will be difficult with the currently favored design of a 5 km core.

Chemistry of heavy elements in the Dark Ages

Primordial molecules were formed during the Dark Ages, i.e. the time between recombination and reionization in the early Universe. The purpose of this article is to analyze the formation of primordial molecules based on heavy elements during the Dark Ages, with elemental abundances taken from different nucleosynthesis models. We present calculations of the full non-linear equation set governing the primordial chemistry. We consider the evolution of 45 chemical species and use an implicit multistep method of variable order of precision with an adaptive stepsize control. We find that the most abundant Dark Ages molecules based on heavy elements are CH and OH. Non-standard nucleosynthesis can lead to higher heavy element abundances while still satisfying the observed primordial light abundances. In that case, we show that the abundances of molecular species based on C, N, O and F can be enhanced by two orders of magnitude compared to the standard case, leading to a CH relative abundance higher than that of HD+ or H2D+.