Cosmic rays pervade the Galaxy and are thought to be accelerated in supernova shocks. The interaction of cosmic rays with dense interstellar matter has two important effects: 1) high energy (>1 GeV) protons produce {gamma}-rays by {pi}0-meson decay;
2) low energy (< 1 GeV) cosmic rays (protons and electrons) ionize the gas. We present here new observations towards a molecular cloud close to the W51C supernova remnant and associated with a recently discovered TeV {gamma}-ray source. Our observations show that the cloud ionization degree is highly enhanced, implying a cosmic ray ionization rate ~ 10-15 s-1, i.e. 100 times larger than the standard value in molecular clouds. This is consistent with the idea that the cloud is irradiated by an enhanced flux of freshly accelerated low-energy cosmic rays. In addition, the observed high cosmic ray ionization rate leads to an instability in the chemistry of the cloud, which keeps the electron fraction high, ~ 10-5, in a large fraction (Av geq 6mag) of the cloud and low, ~ 10-7, in the interior. The two states have been predicted in the literature as high- and low-ionization phases (HIP and LIP). This is the observational evidence of their simultaneous presence in a cloud.
In the past decade, much progress has been made in characterising the processes leading to the enhanced deuterium fractionation observed in the ISM and in particular in the cold, dense parts of star forming regions such as protostellar envelopes. Ver
y high molecular D/H ratios have been found for saturated molecules and ions. However, little is known about the deuterium fractionation in radicals, even though simple radicals often represent an intermediate stage in the formation of more complex, saturated molecules. The imidogen radical NH is such an intermediate species for the ammonia synthesis in the gas phase. Herschel/HIFI represents a unique opportunity to study the deuteration and formation mechanisms of such species, which are not observable from the ground. We searched here for the deuterated radical ND in order to determine the deuterium fractionation of imidogen and constrain the deuteration mechanism of this species. We observed the solar-mass Class 0 protostar IRAS16293-2422 with the heterodyne instrument HIFI as part of the Herschel key programme CHESS (Chemical HErschel Surveys of Star forming regions). The deuterated form of the imidogen radical ND was detected and securely identified with 2 hyperfine component groups of its fundamental transition in absorption against the continuum background emitted from the nascent protostar. The 3 groups of hyperfine components of its hydrogenated counterpart NH were also detected in absorption. We derive a very high deuterium fractionation with an [ND]/[NH] ratio of between 30 and 100%. The deuterium fractionation of imidogen is of the same order of magnitude as that in other molecules, which suggests that an efficient deuterium fractionation mechanism is at play. We discuss two possible formation pathways for ND, by means of either the reaction of N+ with HD, or deuteron/proton exchange with NH.
