The Sloan Digital Sky Survey--III (SDSS--III) Apache Point Observatory Galactic Evolution Experiment (APOGEE) has obtained high resolution (R $sim$ 22,500), high signal-to-noise ratio ($>$ 100) spectra in the H$-$band ($sim$1.5$-$1.7 $mu$m) for about
146,000 stars in the Milky Way galaxy. We have computed spectral libraries with effective temperature ($Trm{_{eff}}$) ranging from 3500 to 8000 K for the automated chemical analy-sis of the survey data. The libraries, used to derive stellar parameters and abundances from the APOGEE spectra in the SDSS--III data release 12 (DR12), are based on ATLAS9 model atmospheres and the ASS$epsilon$T spectral synthesis code. We present a second set of libraries based on MARCS model atmospheres and the spectral synthesis code Turbospectrum. The ATLAS9/ASS$epsilon$T ($Trm{_{eff}}$ = 3500$-$8000 K) and MARCS/Turbospectrum ($Trm{_{eff}}$ = 3500$-$5500 K) grids cover a wide range of metallicity ($-$2.5 $leq$ [M/H] $leq$ $+$0.5 dex), surface gravity (0 $leq$ log $g$ $leq$ 5 dex), microturbulence (0.5 $leq$ $xi$ $leq$ 8 km~s$^{-1}$), carbon ($-$1 $leq$ [C/M] $leq$ $+$1 dex), nitrogen ($-$1 $leq$ [N/M] $leq$ $+$1 dex), and $alpha$-element ($-$1 $leq$ [$alpha$/M] $leq$ $+$1 dex) variations, having thus seven dimensions. We compare the ATLAS9/ASS$epsilon$T and MARCS/Turbospectrum libraries and apply both of them to the analysis of the observed H$-$band spectra of the Sun and the K2 giant Arcturus, as well as to a selected sample of well-known giant stars observed at very high-resolution. The new APOGEE libraries are publicly available and can be employed for chemical studies in the H$-$band using other high-resolution spectrographs.
For the first time we explore the circumstellar effects on the Rb (and Zr) abundance determination in O-rich asymptotic giant branch (AGB) stars by considering the presence of a gaseous circumstellar envelope with a radial wind. A modified version of
the spectral synthesis code Turbospectrum was used to deal with extended atmosphere models and velocity fields. The Rb and Zr abundances were determined from the resonant 7800A Rb I line and the 6474A ZrO bandhead, respectively, in five representative O-rich AGB stars with different expansion velocity and metallicity. By using our new dynamical models, the Rb I line profile (photospheric and circumstellar components) is very well reproduced. Interestingly, the derived Rb abundances are much lower (by 1-2 dex) in those O-rich AGB stars showing the higher circumstellar expansion velocities. The Zr abundances, however, remain close to the solar values. The Rb abundances and Rb/Zr ratios derived here significantly alleviate the problem of the present mismatch between the observations of intermediate-mass (4-8 solar masses) Rb-rich AGB stars and the AGB nucleosynthesis theoretical predictions.
