We investigate wetting phenomena near graphene within the Dzyaloshinskii-Lifshitz-Pitaevskii theory for light gases composed of hydrogen, helium and nitrogen in three different geometries where graphene is either affixed to an insulating substrate, s
ubmerged or suspended. We find that the presence of graphene has a significant effect in all configurations. In a suspended geometry where graphene is able to wet on only one side, liquid film growth becomes arrested at a critical thickness which may trigger surface instabilities and pattern formation analogous to spinodal dewetting. These phenomena are also universally present in other two-dimensional materials.
We aim to understand how the van der Waals force between neutral adatoms and a graphene layer is modified by uniaxial strain and electron correlation effects. A detailed analysis is presented for three atoms (He, H, and Na) and graphene strain rangin
g from weak to moderately strong. We show that the van der Waals potential can be significantly enhanced by strain, and present applications of our results to the problem of elastic scattering of atoms from graphene. In particular we find that quantum reflection can be significantly suppressed by strain, meaning that dissipative inelastic effects near the surface become of increased importance. Furthermore we introduce a method to independently estimate the Lennard-Jones parameters used in an effective model of He interacting with graphene, and determine how they depend on strain. At short distances, we find that strain tends to reduce the interaction strength by pushing the location of the adsorption potential minima to higher distances above the deformed graphene sheet. This opens up the exciting possibility of mechanically engineering an adsorption potential, with implications for the formation and observation of anisotropic low dimensional superfluid phases.
